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tween steady and oscillatory states, and marked sensitivity to stirring rate. Thiocyanate shows none of these features. A mechanistic explanation of the chlorite-bromide oscillations seems within reach given the reactions's similarity to the chlorite-iodide reaction and the success of numerical simulations' ' , 1 2 of batch behavior in the chlorite-bromide system. In contrast, very little is kn...

A simple and sensitive kinetic-spectrophotometric method is described for the determination of vanadium and the possible mechanism of catalytic reaction is proposed. The method is based on the vanadium(V)-catalyzed oxidation of 1,8-diaminonaphthalene (DNA) by potassium bromate (Tiron as activator) at pH 3.8 and 40 degrees C. The reaction was monitored spectrophotometrically by measuring the inc...

Journal of the American Chemical Society is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Systematic design of chemical oscillators. 10. Minimal bromate oscillator: bromate-bromide-catalyst Miklos Orban, Patrick De Kepper, and Irving R. Epstein J. Am. Chem. Soc., 1982, 104 (9), 2657-2658• DOI: 10.1021/ja00373a063 • Publication Date (Web): 01 May 20...

In regions characterized by water scarcity, such as coastal Southern California, groundwater containing chromophoric dissolved organic matter is a viable source of water supply. In the coastal aquifer of Orange County in California, seawater intrusion driven by coastal groundwater pumping increased the concentration of bromide in extracted groundwater from 0.4 mg l⁻¹ in 2000 to over 0.8 mg l⁻¹ ...

Three simple and sensitive spectrophotometric methods are proposed for the determination of atenolol (ATN) in bulk drug and tablets. The methods are based on the bromination of ATN by the bromine generated in situ by the action of the acid on the bromate-bromide mixture followed by the determination of unreacted bromine by reacting with a fixed amount of either meta-cresol purple (MCP) and meas...

A simple, sensitive, rapid and reliable method has been developed for spectrophotometric determinations of As(III) in the presence of As(V) based on its inhibition effect on the redox reaction between bromate and hydrochloric acid. The decolorization of methyl orange by the reaction products was used to monitor the reaction spectrophotometrically at 525 nm. The method allows the determination o...

The occurrence of Cryptosporidium in raw waters and bromate formation during ozonation of bromide-containing waters leads to a difficult optimisation of ozonation processes. On the one hand inactivation of Cryptosporidium requires high ozone exposures, on the other hand under these conditions bromate formation is favored. In order to overcome this problem we need information about (i) the oxida...

This manuscript addresses identification, analysis, formation and occurrence of key disinfection byproducts (DBPs) formed during chlorination and/or ozonation of both natural seawater (NSW), and synthetic high- and low-bromide saltwater (HBSW and LBSW, respectively). In this study, several groups of water disinfection byproducts were studied, including haloacetic acids (HAAs), halonitromethanes...