One pot asymmetrical double allylations of sodium sulfide catalyzed by an iridium complex along with a combination of caesium fluoride and water in dichloromethane have been realized and the double allylation products with two C-S bond chiral centers were obtained in 67-99% yields with b/l 81/19-99/1, dr 85/15-99/1, and 96-99% ee.

A new route to α-alkyl-α-fluoromethylenebisphosphonates, 2 has been developed starting from commercially available tetraethyl fluoromethylenebisphosphonate (1), and alkyl halides using either caesium carbonate in DMF or sodium dimsyl. De-esterification of 2 provided biologically important α-alkyl-α-fluoromethylenebisphosphonic acid, 3, while alkoxide-induced carbon-phosphorus bond cleavage of 2...

An efficient reagent-controlled methodology for generating highly substituted diverse scaffolds from a common substrate has been developed; thus, treatment of a common precursor with different desilylating reagents, such as ammonium fluoride, caesium fluoride and PPTS, triggers different domino reaction sequences, yielding highly substituted pyridines, phenols and benzopyrans, respectively; the...

Caesium magnesium orthophosphate is built up from MgO(4) and PO(4) tetra-hedra (both with . m. symmetry) linked together by corners, forming a three-dimensional framework. The Cs atoms have .m. site symmetry and are located in hexa-gonal channels running along the a- and b-axis directions.

With recent reports of alkali metal amides used in homogeneous catalytic chemistry where the reactivity down group one is dependent on identity, esoteric rubidium and caesium are finding new admirers amongst chemists who usually study lithium, sodium, potassium utility amides. Here, as a forerunner to their exploitation catalysis, we report X-ray crystallographic NMR solution structures 1-metal...