fine particles silicoaluminophosphate-34 were synthesized by hydrothermal sol-gel method. the effect of crystallization time, as one of the important synthesis factors on particle size and crystallinity, kinetic and equilibrium adsorption, and selectivity of co2 / ch4 has been studied in this work. the adsorption isotherms are obtained at moderate gauge pressures (100-3000 kpa) and temperatures...

Methanol-to-olefins is a promising process that has attracted the attention of many research groups in last years. Zeolites are primary catalyst for this process, and SAPO-34 one most used because its high selectivity toward C2–C4 olefins. As drawback, it deactivates quickly forces to work alternately using reaction regeneration cycles. The mechanism by which still on debate, further needs be d...

In situ synchrotron infrared microspectroscopy on single crystals of SAPO-34 reveals that a carbene insertion mechanism is responsible for the first carbon–carbon bond formation from surface methoxy groups.

The methanol-to-olefin process is a showcase example of complex zeolite-catalyzed chemistry. At real operating conditions, many factors affect the reactivity, such as framework flexibility, adsorption of various guest molecules, and competitive reaction pathways. In this study, the strength of first principle molecular dynamics techniques to capture this complexity is shown by means of two case...

Micro-/meso-/macroporous Cu-containing SAPO-34 prepared by the post-synthetic modification of a commercial support with diethylamine (DEA), shows enhanced activity in NH 3 -SCR-DeNO x .