Chemical Looping with Oxygen Uncoupling (CLOU) is an advanced approach proposed for improving the utilization degree of solid fuels and speeding up the reaction rate in Chemical-Looping Combustion technology (CLC). In CLOU system, OC circulates between fuel reactor (FR) and air reactor (AR), providing gaseous oxygen for the combustion of fuels (in FR) and then being regenerated by absorbing gas...

Oxygen release from metal oxides at high temperatures is relevant to many thermally activated chemical processes, including chemical-looping combustion, solar thermochemical cycles and energetic thermite reactions. In this study, we evaluated the thermal decomposition of nanosized metal oxides under rapid heating (~10(5) K s(-1)) with time-resolved mass spectrometry. We found that the effective...

In this work it is analyzed the performance of an iron waste material as oxygen carrier for a chemical-looping combustion (CLC) system. CLC is a novel combustion technology with the benefit of inherent CO2 separation that can be used as a source of energy for the methane steam reforming process (SR). The tail gas from the PSA unit is used as fuel in the CLC system. The oxygen carrier behaviour ...

Chemical looping combustion is a promising technology for power production with integrated CO2 capture. High overall efficiencies can be reached, if the CLC reactors are operated at elevated pressures and high temperature, which can be accommodated in packed bed reactors. More possible oxygen carriers can be selected if the desired temperature rise for power production is achieved in a two stag...

The behavior of Fe2O3/Al2O3 particles as oxygen carriers (OCs) for CO chemical looping combustion (CLC) under different reaction temperatures (700 ◦C, 800 ◦C, 900 ◦C, and 1000 ◦C) were tested in a lab-scale fluidized bed and a thermogravimetric analysis (TGA) unit. The results show that the oxygen carrier presents the highest reactivity at 800 ◦C, even after 30 cycles of redox reaction in a flu...

Chemical-Looping Combustion (CLC) is an emerging technology for CO2 capture because separation of this gas from the other flue gas components is inherently to the process and thus no energy is expended for the separation. For its use with coal as fuel in power plants, a process integrated by coal gasification and CLC would have important advantages for CO2 capture. This paper presents the combu...