1. The preparation and characterization of manganese, iron, cobalt, nickel, copper and zinc metalloporphyrins is described. Ferrihaem was also esterified with pyrid-4-ylpropanol and the derivative characterized as the diester. 2. Complexes of these various porphyrins, as well as protoporphyrin IX, with apomyoglobin were formed and the resulting artificial myoglobins characterized. 3. Very littl...

A novel cation exchange fiber supported solid membrane was developed for transport of cobalt, manganese and nickel metal ions. Fiber supported solid membrane was prepared by chemically modifying the cellulose fibers with citric acid. In the fiber supported solid membrane, the diffusion by capillary action by keeping the liquid phase in the porous solid fiber and ion exchange mechanism were used...

The potential use of synergistic mixtures of reagents for the solvent extraction of nickel (and cobalt) from lateritic leach liquors was pointed out in the early 1980s by Grinstead, who used dinonylnaphthalene sulphonic acid in conjunction with some 2-pyridyl compounds for the recovery of these metals from slightly acidic solutions1,2. Shortly thereafter, studies at Mintek revealed marked syner...

A brief observation of the developments in mining systems and technology in the past 2 to 4 years is presented. Discussions on the development of other deep-ocean resources that are somewhat similar to nodule production also include gas hydrates, Cobalt-rich manganese crusts, hydrothermal vents and deep-ocean water upwelling (DOW). Previous reviews of deep-ocean mining can be found in Chung (19...

In natural photosynthesis, the oxygen evolving center is a tetranuclear manganese cluster stabilized by amino acids, water molecules and counter ions. However, manganese complexes are rarely exhibiting catalytic activity in water oxidation conditions. This is also true for the family of water oxidation catalysts (WOCs) obtained from POM chemistry. We have studied the activity of the tetranuclea...

A series of small and well defined cobalt nanoparticles were synthesized by the chemical reduction of cobalt salts in water using NaBH4 as a reducing agent and using various polymeric stabilizers. The obtained nanocatalysts of similar mean diameters (ca. 2.6 nm) were fully characterized and tested in the aqueous phase Fischer-Tropsch Synthesis (AFTS). Interestingly, the nature and structure of ...

Microbiological leaching of synthetic cobaltous sulfide (CoS) was investigated with a pure strain of Thiobacillus ferroxidans. The strain could not grow on CoS-salts medium in the absence of ferrous ions (Fe). However, in CoS-salts medium supplemented with 18 mM Fe, the strain utilized both Fe and the sulfur moiety in CoS for growth, resulting in an enhanced solubilization of Co. Cell growth on...

A systematic analysis of the mineral resource base (MRB) strategically important minerals for Ukrainian economy is carried out. Four categories strategic from point view their investment attractiveness are identified: traditional (iron, manganese, titanium, uranium, kaolin, sand molding, building stones, quartz raw materials, refractory clay); highly promising (rare earths, zirconium and hafniu...

A study was carried out to understand the mineral constituent variations under cobalt treatment in Vigna mungo (L.) Hepper. The experiments were conducted in earthen pots and lined the inner surface with polythene sheet. Each pot contains 3 kg of air dried soil. Blackgram plants were raised in these pots containing soils amended with different concentrations of cobalt (0, 50, 100, 150, 200 and ...