In geological storage of carbon dioxide (CO2), the buoyant CO2 plume eventually accumulates under the caprock. Due to interfacial tension between the CO2 phase and the water phase, a capillary transition zone develops in the plume. This zone contains supercritical CO2 as well as water with dissolved CO2. Under the plume, a diffusive boundary layer forms. We study how cross-flow between the capi...

A theoretical model for carbon dioxide (CO2) migration in tilted aquifers with groundwater flow is presented to evaluate the injection of CO2 into a geological formation. Capillary force in the flow of two immiscible fluids in a porous medium creates a saturation transition zone, where the saturation changes gradually. A vertical equilibrium assumption is employed to solve for the capillary pre...

Microporous carbon materials with extremely small pore size are prepared by employing polyaniline as a carbon precursor and KOH as an activating agent. CO(2) sorption performance of the materials is systematically investigated at the temperatures of 0, 25 and 75 °C. The prepared carbons show very high CO(2) uptake of up to 1.86 and 1.39 mmol g(-1) under 1 bar, 75 °C and 0.15 bar, 25 °C, respect...

CO2 levels are expected to rise (a) in surface waters of the oceans as atmospheric accumulation continues or (b) in the deep sea, once industrial CO2 dumping is implemented. These scenarios suggest that CO2 will become a general stress factor in aquatic environments. The mechanisms of sensitivity to CO2 as well as adaptation capacity of marine animals are insufficiently understood. Here, we pre...

In Escherichia coli, succinic acid is synthesized by CO2 fixation-based carboxylation of C3 metabolites. A two-step process is involved in CO2 integration: CO2 uptake into the cell and CO2 fixation by carboxylation enzymes. The phosphoenolpyruvate (PEP) carboxylase (PPC) and carboxykinase (PCK) are two important carboxylation enzymes within the succinate synthetic pathway, while SbtA and BicA a...

Using CO2 data from the Atmospheric Infrared Sounder (AIRS), it is found for the first time that the mid-tropospheric CO2 concentration is ~1 part per million by volume higher during dry years than wet years over the southwestern USA from June to September. The mid-tropospheric CO2 differences between dry and wet years are related to circulation and CO2 surface fluxes. During drought conditions...

Adsorbents prepared easily by impregnation of fumed silica with polyethylenimine (PEI) are promising candidates for the capture of CO2 directly from the air. These inexpensive adsorbents have high CO2 adsorption capacity at ambient temperature and can be regenerated in repeated cycles under mild conditions. Despite the very low CO2 concentration, they are able to scrub efficiently all CO2 out o...

A series of highly branched trichain sulfosuccinate surfactants have been synthesized and studied in condensed CO2 and aqueous environments. Aqueous critical micelle concentrations (CMCs) showed a general trend of increasing CMC with decreasing chain length, whereas increased branching appeared to increase solubility in CO2 and aid the dispersion of water. Near infrared spectra confirmed observ...

A high pressure stage for CO2 processing has been designed, certified according to Canadian Standards Association (CSA) regulations, and built by an approved pressure-vessel manufacturer. This stage is designed to fit onto a normal laboratory powder diffractometer. Together with the use of MoKα radiation and a Bruker Våntec PSD detector, this stage will allow extensive studies on the kinetics o...