Aiming at providing a comprehensive study of the influence of the cation symmetry and alkyl side chain length on the surface tension and surface organization of ionic liquids (ILs), this work addresses the experimental measurements of the surface tension of two extended series of ILs, namely R,R'-dialkylimidazolium bis[(trifluoromethyl)sulfonyl]imide ([C(n)C(n)im][NTf2]) and R-alkyl-3-methylimi...

At the end of the final spin cycle of the laundry process, the residual moisture content (RMC) of fabric is directly related to the dynamic surface tension of the residual water in the fabric. The LaPlace equation for capillary rise predicts that the capillary rise of solutions in a capillary is proportional to the surface tension at the air-liquid interface. If fabric can be considered to be a...

The gas-liquid phase transition of the three-dimensional Lennard-Jones particles system is studied by molecular dynamics simulations. The gas and liquid densities in the coexisting state are determined with high accuracy. The critical point is determined by the block density analysis of the Binder parameter with the aid of the law of rectilinear diameter. From the critical behavior of the gas-l...

The interfacial tension of surfactant solutions is decreased with increasing surfactant concentration to obtain the critical micelle concentration (CMC). After that, the CMC values does not alter much. So this concentration is a critical point during surfactant flooding that is one of the chemical EOR techniques. The reduction of the CMC value is taken into consideration, since the surfactant f...

Experimental measurements of the surface tension of six imidazolium-, pyridinium-, pyrrolidinium-, and phosphonium-based ionic liquids (ILs) with NTf2 as the common anion and their dependence with the temperatures of (293 to 353) K at atmospheric pressure are presented. The set of selected ILs was chosen to investigate the influence of the length and position of the cation alkyl chain and the c...

Treated sea water is the most significant source of water and surfactant floods. The various chemicals employed in treatment plants should be compatible with surfactant systems. Based on surface tension experiments, the activity of these chemicals is examined over a wide range of concentrations in different solutions, including distillated water, sea water by using three types of surfactant mix...

Phase equilibria of a square-well fluid in planar slit pores with varying slit width are investigated by applying the grand-canonical transition-matrix Monte Carlo (GC-TMMC) with the histogram-reweighting method. The wall-fluid interaction strength was varied from repulsive to attractive such that it is greater than the fluid-fluid interaction strength. The nature of the phase coexistence envel...

– Phenomenological nucleation theories are considered from the viewpoint of Gibbs’ surface thermodynamics. We point out, in defining the critical nucleus, that it is important to make a distinction between the number of molecules enclosed by the surface of tension and the excess number of molecules over the uniform vapor phase. We show that the Kelvin equation should be employed in determining ...

We have investigated CCN properties of internally mixed particles composed of one organic acid (oxalic acid dihydrate, succinic acid, adipic acid, citric acid, cis-pinonic acid, or Nordic reference fulvic acid) and one inorganic salt (sodium chloride or ammonium sulphate). Surface tension and water activity of aqueous model solutions with concentrations relevant for CCN activation were measured...