The structures of [M(H2O)2(15-crown-5)](NO3)2, M = Cu, Zn, Mg and Co, and 15-crown-5 = 1,4,7,10,13-pentaoxacyclopentadecane, have been redetermined at 294 and 90 K. The four structures, and a second form of the Cu structure, have been reported in the literature, but are all incorrect in some significant way. The structures, which all have at least two independent formula units (i.e. Z' > or = 2...

Sixteen lipophilic N-(X)sulfonyl carbamoyl lariat ethers with polyether ring sizes of 12-crown-4, 14-crown-4, 15-crown-5, and 18-crown-6 are utilized for competitive alkali metal cation extractions from aqueous solutions into chloroform. Variation of the electron-withdrawing properties of X in the series of methyl, phenyl, 4-nitrophenyl, and trifluoromethyl allows the influence of the acidity o...

Treatment of K[N(SiMe3)2] with N,N′-bis(2,6-difluorophenyl)formamidine (DFFormH) in toluene, resulted in the formation of [K(DFForm)]∞ (1) as a poorly soluble material. Upon dissolution in thf and layering with n-hexane, 1 was crystallised and identified as a two-dimensional polymer, in which all fluorine and nitrogen atoms, and also part of one aryl group, bridge between four symmetry equivale...

Previous studies of tooth size in twins and their families have suggested a high degree of genetic control, although there have been difficulties separating the various genetic and environmental effects. A genetic analysis of variation in crown size of the permanent incisors of South Australian twins was carried out, with structural equation modeling used to determine the relative contributions...

BACKGROUND/AIM Few studies have assessed the incidence and risk factors to crown fractures in preschool children. The aim of this study was to estimate the incidence of crown fracture in the primary dentition over a 1-year follow-up period, identify risk factors, and test the hypothesis that children with previous crown fracture are more prone to experience further cases of crown fracture indep...

An increase in the frequency and magnitude of extreme weather events, such as major ice storms, can have severe impacts on southern forests. We investigated the damage inflicted by a severe ice storm that occurred in February 2014 on two loblolly pine (Pinus taeda L.) ideotypes in Cross, South Carolina located in the southeastern coastal plain. The ‘‘narrow crown” ideotype allocates more resour...

The final hot strip profile is a superposition of the roll initial crown, the roll bending and flattening crown, the roll wearing crown and the roll thermal crown. In this research, linear regression models are proposed to predict the roll force, the roll wearing crown and the roll thermal crown using experimental data provided by Mobarake Steel Complex (MSC). The Euler-Bernoulli beam theory ba...

Crown-ethers have recently been used to assemble porous liquids (PLs), which are liquids with permanent porosity formed by mixing bulky solvent molecules (e.g., 15-crown-5 ether) with solvent-inaccessible organic cages. PLs and crown-ethers belong to a novel class of materials, which can potentially be used for gas separation and storage, but their performance for this purpose needs to be asses...

To analyze the main variables affecting crown biomass, we measured crown biomass and a number of variables describing tree size, such as stem diameter at breast height (D), tree height (H), crown width (Cw) and crown length (Cl), from 754 sample trees of four pine species in China, specifically, Pinus massoniana, P. yunnanensis, P. tabulaeformis and P. elliottii. In addition, we developed indiv...

PURPOSE The purpose of this study was to analyze the retention force changes and wear behaviours of double-crown systems over long-term use. MATERIALS AND METHODS Ten groups, each consisting of six samples, were evaluated. Specifically, casting gold alloy primary crown - casting gold alloy secondary crown (AA), laser sintering primary crown - laser sintering secondary crown (LL), casting Cr a...