A new highly selective and sensitive fluorescent probe for Cu2+, N-n-butyl-4-(1'-cyclooctene-1',3',6'-triazole)-1,8-naphthalimide (L), was synthesized and evaluated. The structure of compound L was characterized via IR, ¹H-NMR, 13C-NMR and HRMS. The fluorescent probe was quenched by Cu2+ with a 1:1 binding ratio and behaved as a "turn-off" sensor. An efficient and sensitive spectrofluorometric ...

Developing an innovative "Test Paper" based on virgin nanoporous silicon (NPSi) which shows intense visible emission and excellent fluorescence stability. The visual fluorescence quenching "Test Paper" was highly selective and sensitive recognizing Cu2+ at μmol/L level. Within the concentration range of 5 × 10-7 ~50 × 10-7mol/L, the linear regression equation of IPL = 1226.3-13.6[CCu2+] (R = 0....

A new light-emitting polyacetylene bearing imidazole moieties in the side chain (), was conveniently prepared through a postfunctionalization strategy, as a sensory polymer to selectively report the presence of Cu2+ (with a detection limit of 1.48 ppm) based on the fluorescence "turn-off". Interestingly, the quenched luminescence of by Cu2+ could be turned on after the addition of CN-, making a...

in the present study, a new chemically modified carbon paste electrode (cpe) is constructed for rapid, accurate, simple, highly sensitive, and selective determination of mo (vi) using differential pulse voltammetry. the electrode was prepared using magnetic nickel zinc ferrite nanocomposite (ni0.5zn0.5fe2o4), as the modifier in cpe (ni0.5zn0.5fe2o4/cpe). mo (vi) was determined after preconcentr...

sol-gel and polymeric membrane electrodes, based on thiacalix[4]arene as a neutral carrier, weresuccessfully developed for the detection of vo2+ in aqueous solutions. the sol-gel and pvcmembrane electrodes exhibited linear response with nernstian slopes of 29.3 and 28.4 mv perdecade, respectively, within the vanadyl ion concentration ranges from 1.0 × 10-6 to 1.0 × 10-1mol dm-3 and from 1.0 × 1...

In this work a new chemically modified carbon paste electrode was constructed for accurate, simple, sensitive and selective determination of molybdenum (VI) ions. The results of modified electrode by an ion imprinted polymer were compared with those obtained with carbon paste electrode. The results showed the stripping peak currents had a dramatic increase at the modified electrode. Under the o...

The electropolishing behaviour of 73 brass was studied by means of a rotating cylinder electrode (RCE) in a 70 vol % H3PO4 solution at 27 ◦C. Owing to the formation of a blue Cu2+-rich layer on the brass-RCE, an obvious transition peak was detected from kineticto diffusion-controlled dissolution in the anodic polarisation curve. Electropolishing was conducted at the potentials located at the tr...

In this study a simple, highly sensitive, and selective electrochemical method was developed for determination of the low concentration curcumin (CUR) using a poly(vanillin-co-caffeic acid) p(Van-CA) modified platinum electrode. Electrode modification was carried out electrochemically with cyclic voltammetry (CV) method. For this purpose; a solution of 6 mM vanillin (Van) and 6 mM caff...

an iodide ion-selective pvc membrane sensor based on copper (π)-bis-nphenilsalicyldenaminatocomplex as a novel sensing material is successfully developed. theelectrode showed a good selectivity for iodide ion with respect to common inorganic anions. thesensor exhibited a good linear response with slope of _58.6 ± 0.4 mv per decade over theconcentration range of 5.0 × 10-6 to 1.0 × 10-1 mol l-1,...

A chemically modified carbon paste electrode with multiwall carbon nanotube (MWCNT) was prepared and used as a sensor for Cu2+  ion. The unique chemical and physical properties of CNT have paved the way  to  new  and  improved  sensing  devices.  A  central  composite chemometrics  design  was  applied  for  multivariate  optimization  of the  effects  of  three  significant  parameters  (...