A model is developed based on a two-stage hydrogenation of pyrolysis gasoline to obtain a C6-C8 cut suitable for extraction of aromatics. The first stage hydrogenation takes place in a trickle bed reactor while the second stage hydrogenation is carried out in a two compartment fixed bed reactor in which hydrogenation of olefins takes place in the first compartment while the sulphur is eliminate...

This paper presents the results of detailed studies possibility using Lewis acid AlCl3as a promoter catalytic three-component system PdCl2(PPh3)2–PPh3–AlCl3in hydroethoxycarbonylation reaction cyclohexene at low carbon monoxide pressures (2.5 MPa). As result high activity was established and proceeds regioselectively with formation ethyl ether cyclohexanecarboxylic acid. The optimal conditions ...

Cyclohexanol is an organic chemical intermediate product widely used in chemical<br /> industry and commonly produced by cyclohexene hydration. Because of the low mutual<br solubility water, reaction limited equilibrium,<br which has disadvantage conversion cyclohexene. In this paper, hydration catalysed A-36 cation exchange resin catalyst was analysed Aspen Plus V8.6 simulation sof...

Investigating the composition of organic aerosol resulting from cyclohexene ozonolysis: low molecular weight and heterogeneous reaction products J. F. Hamilton, A. C. Lewis, J. Reynolds, L. J. Carpenter, and A. Lubben Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK Bruker Daltonics, Banner Lane, Coventry, CV4 9GH, UK Received: 26 April 2006 – Accepted: 16 May 2006 – ...

In the crystal structure of the title compound, C(19)H(20)N(2)O(3)·C(3)H(6)O, mol-ecules are linked into inversion dimers with an R(2) (2)(12) motif by pairs of N-H⋯N hydrogen bonds. These dimers are further connected into chains running along the a axis by N-H⋯O hydrogen bonds. C-H⋯N and C-H⋯π inter-actions also feature in the packing. The cyclohexene ring adopts nearly an envelope conformatio...

The mechanism of the enantioselective deprotonation of cyclohexene oxide with isopinocampheyl-based chiral lithium amide was studied by quantum chemical calculations. The transition states of eight molecules were fully optimized at the ab initio HF/3-21G and density functional B3LYP/3-21G levels with Gaussian 98. The activation energies were calculated at the B3LYP/6-31+G(3df,2p)//B3LYP/3-21G l...

In the RCM reactions of a series of simple α,ω-dienes, the relative order of reactivity has been unambiguously determined showing that cyclohexene forms faster than cyclopentene or cycloheptene. 1,5-Hexadiene inhibits the RCM of 1,7-octadiene; 1,5-hexadiene cannot progress to the RCM product (cyclobutene) but forms an unexpectedly stable cyclic η(2)-complex.

1,11-Dien-6-ynes undergo cycloisomerization in the presence of the cobalt catalytic system CoBr2/phosphine ligand/Zn/ZnI2 giving cyclohexene, diene or cyclopropane structures depending on the type of the phosphine ligand. This unpredictable behaviour suggests that, although the availability of the cobalt catalytic system is appealing, the development of well-defined catalysts is desirable for f...