Coordination compounds with mixed ligands were synthesized 2A group (Mg2+, Ca2+, Ba2+, Sr2+) alkaline earth metal cations of coumarilic acid and nicotinamide ligands. Afterward, the structural properties these new molecules investigated by melting point, elemental analysis, infrared spectroscopy, thermal analysis (TGA / DTA) curves, powder X-ray diffraction (P-XRD) spectroscopy. It has been sug...

The structure of the Mg2+ complex of yeast enolase has been determined from crystals grown in solutions of poly(ethylene glycol) at pH 8.1. Crystals belong to the space group P2(1) and have unit cell dimensions a = 72.5 A, b = 73.2 A, c = 89.1 A, and beta = 104.4 degrees. There is one dimer in the asymmetric unit. The current crystallographic R-factor is 19.0% for all recorded data to 1.9 A res...

[1] Predicting the transport of reactive chemicals in subsurface porous media requires accurate adsorption models. This study compares the ability of various cation exchange models to quantitatively capture the transport behavior of major cations (i.e., calcium and sodium) in soil laboratory columns over a wide range of pore water composition. Experimental breakthrough curves were compared with...

$3{d}^{2}$ vanadate perovskites exhibit an unusual phase diagram where the low temperature orbital and spin orders are strongly dependent upon rare-earth cation size. Here, we demonstrate delicate role of strain in epitaxial ${\mathrm{LaVO}}_{3}$ films by performing low-energy muon spectroscopy ellipsometry measurements. The electronic structure is revealed measurement multipeak charge excitati...

rapidly at room temperature (RT) to provide ready-to-read results within 5 minutes without the need for incubation at elevated temperatures (Figure 1). Similar to the BCA assay, the Pierce Rapid Gold BCA Protein Assay combines the well-known reduction of Cu2+ to Cu+ by proteins in an alkaline medium (biuret reaction) with highly sensitive and selective colorimetric detection by a new copper che...

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The crystal structure of EuRu(4)P(12) is isotypic with filled skutterudite structures of rare earth transition metal poly-phosphides: RFe(4)P(12) (R = Ce, Pr, Nd, Sm and Eu), RRu(4)P(12) (R = La, Ce, Pr and Nd) and ROs(4)P(12) (R = La, Ce, Pr and Nd). The Ru cation is coordinated by six P anions in a distorted octa-hedral manner. The partially occupied Eu position (site occupancy 0.97) is enclo...

Electrochemiluminescence (ECL) of a series of ruthenium(II) diimine complexes with appended crown ethers derived from 1,10-phenanthroline was studied via either the annihilation route or the coreactant schemes, and the ECL efficiency has been determined. The effect of an FSN surfactant on the ECL properties was also studied in buffer solutions. The effect of cation binding on the ECL behavior w...

Rubidium ytterbium(III) tetra-kis-(polyphosphate), RbYb(PO3)4, was synthesized by solid-state reaction. It adopts structure type IV of the MRE(PO3)4 (M = alkali metal and RE = rare earth metal) family of compounds. The structure is composed of a three-dimensional framework made up from double spiral polyphosphate chains parallel to [10-1] and irregular [YbO8] polyhedra. There are eight PO4 tetr...