The electrochemical oxidation of methyl catechol in the presence of 2-thiouracil (as a nucleophile) has beenperformed in aqueous solutions using cyclic voltammetry and controlled-potential coulometric techniques.The electrochemical behavior of methyl catechol in the presence of 2-thiouracil was investigated. Theelectrochemical synthesis of this compound has been successfully performed in an und...

In situ electropolymerization as a facile synthetic procedure has been used to obtain highly active compositesof ionic liquid functionalized graphene oxide(FGO)and poly ortho aminophenol (POAP). Surface and electrochemical analysis have been used for characterisation of FGO-POAP composite film. Nickel was accumulated by complex formation between Ni (II) in solution and amines sites in the polym...

We present electrochemical synthesis of super water-repellent poly(alkylpyrrole) films which exhibit excellent environmental stability in terms of contact angle (>150 degrees ) for water. The poly(alkylpyrrole) films synthesized under an optimized electrochemical condition consisted of thousands of micro-scaled 'needles' which densely aligned by shoulder to shoulder. The surface of the aligned ...

The electrochemical behavior of rhodium at low-temperature carbamide-chloride and acetamide-chloride melts was investigated. It was found that, during rhodium anodic dissolution in carbamide and acetamide containing chloride melts, mixed complexes [Rh(NH3)4Cl2]+ of quasi-octahedral symmetry D4h are produced. The composition and structure of nascent complex ions have been studied. During electro...

This paper reports syntheses, crystal structures and electrochemical results for two ferrocene(Fc)-modified pyrimidine nucleosides that could potentially be used for investigating electron transfer in DNA. Fc was directly attached to the 5-position of deoxyuridine and deoxycytidine via the Stille coupling reaction. Fc-modified uridine was incorporated into DNA trinucleotides with standard solid...