نتایج جستجو برای: electrospray
تعداد نتایج: 8566 فیلتر نتایج به سال:
Electrospray thrusters utilize a strong electric field to extract and accelerate charged particles contained at a needle tip in a liquid state [1]. Electrospray thrusters are one of the few types of electric propulsion systems that can offer high specific impulses (i.e. >1000 seconds) whilst still being scalable down to fit within a 1U CubeSat form structure. These small electrospray thrusters,...
Two new phenyl glycosides, mangliesides A and B (1, 2), a new ionol glycoside, manglieside C (3), two new lignan glycosides, mangliesides D and E (4, 5), were isolated from the leaves of Manglietia phuthoensis, along with two known lignans, 3-methoxymagnolol (6) and obovatol (7). Their structures were established by means of 1D and 2D NMR, electrospray ionization (ESI)-MS and HR-ESI-MS experime...
Laser electrospray mass spectrometry (LEMS) is demonstrated for pharmaceutical samples at atmospheric pressure. A nonresonant, femtosecond duration laser pulse vaporizes native samples at atmospheric pressure into an electrospray plume for ionization with subsequent transfer into a time-of-flight mass spectrometer. The active ingredients in pharmaceutical tablets were detected in the presence o...
Liquid chromatography coupled to electrospray ionisation high resolution mass spectrometry is an extremely powerful technique for both targeted and non-targeted analysis of organic aerosol.
0017-9310/$ see front matter 2011 Elsevier Ltd. A doi:10.1016/j.ijheatmasstransfer.2011.02.038 ⇑ Corresponding author. Tel.: +1 203 432 4384; fax E-mail address: [email protected] (A. G The challenge of effectively removing high heat flux from microelectronic chips may hinder future advancements in the semiconductor industry. Spray cooling is a promising solution to dissipate high heat ...
The basic principles underlying the electrospray process are reviewed without recourse to detailed discussion of mechanisms. The essential features of the practical implementation of electrospray (at various solution Ñow rates) are described and the nature of the resultant gas-phase ion population is discussed. The generation by electrospray of multiply charged ions creates complications in tha...
Full-dimensional computational fluid dynamics (CFD) simulations are presented for nano electrospray ionization (ESI) with various emitter designs. Our CFD electrohydrodynamic simulations are based on the Taylor-Melcher leaky-dielectric model, and the volume of fluid technique for tracking the fast-changing liquid-gas interface. The numerical method is first validated for a conventional 20 μm in...
Internal energy changes during the electrospray process have been studied. Our results suggest that, contrary to conventional wisdom, ions that are quite hot are formed in electrospray, even without acceleration in the cone-skimmer region. The main role of the curtain gas seems to be not to break up existing clusters but, rather, to cool down the nascent ions and to prevent cluster formation by...
This short review aims to summarize the current developments and applications of mass spectrometry-based methods for in situ profiling and imaging of plants with minimal or no sample pre-treatment or manipulation. Infrared-laser ablation electrospray ionization and UV-laser desorption/ionization methods are reviewed. The underlying mechanisms of the ionization techniques-namely, laser ablation ...
Electrospray ionization (ESI) has revolutionized mass spectrometry (MS), providing a facile method for the ionization of macromolecules for analysis by mass. The development of nanoESI-MS has further extended the utility of ESI-MS, permitting the analysis of small-volume samples with enhanced sensitivity over conventional ESI-MS. Traditional nanoESI-MS experiments use pulled-glass capillary emi...
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