Photoinitiated silane-ene chemistry has the potential to pave the way toward spatially resolved organosilicon compounds, which might find application in biomedicine, microelectronics, and other advanced fields. Moreover, this approach could serve as a viable alternative to the popular photoinitiated thiol-ene chemistry, which gives access to defined and functional photopolymer networks. A difun...

Cell enrichment is currently in high demand in medical engineering. We have reported that non-blood cells can attach to a blood-compatible poly(2-methoxyethyl acrylate) (PMEA) substrate through integrin-dependent and integrin-independent mechanisms because the PMEA substrate suppresses protein adsorption. Therefore, we assumed that PMEA analogous polymers can change the contribution of integrin...

In order to meet the anticorrosion and wear resistance requirements of petroleum pipelines, we selected a polymer (FC) containing difunctional hydroxyl propyl acrylate (HPA) perfluoroalkyl ethyl (TEAc-N) free radical polymerization prepare hydrophobic fluorocarbon chain oil special functional group. Combined with tetrafluororesin (F4), hydrophobic, wear-resistant corrosion-resistant properties ...

In this article, poly(methyl methacrylate/n-butyl acrylate) copolymer (PMA) is being considered for utilizing as a waterproof adhesive layer (WAL) on the steel bridge deck. Toughness modification of methacrylate-based (MMA) was carried out by adding n-butyl acrylate (nBA) using emulsion polymerization method to overcome its brittleness. The “Asphalt mixture-MMA-Steel plate” interfacial morpholo...

Two hybrid sol-gel coatings, one acrylate-based and the other epoxy-based, were synthesized deposited on two cast aluminum-silicon alloys, Al-Si9-Cu3 Al-Si7-Mg0.3. Field immersion testing was performed in Adriatic Sea lasted 8 months. Coatings characterized before after terms of morphology, structure, composition, electrochemical properties artificial seawater. The level biofouling documented, ...

Epoxy is a versatile resin used in different fields such as coatings, colors, colorants, and composites. Adding nano-scale fillers/additives to the epoxy has valued epoxy coatings for engineering applications, and opened the time of advanced epoxy-based nanocomposite coatings. In the present work, graphene oxide GO was chemically functionalized with starch, as a natural polymer, and added to th...

In the title compound, C(18)H(18)O(2), the methyl acrylate substituent adopts an extended E conformation with all torsion angles close to 180°. The mean plane of the acrylate unit and the phenyl ring are approximately orthogonal to each other, making a dihedral angle of 81.40 (6)°. The position of the carbonyl group with respect to the olefinic double bond is typically S-trans. The crystal pack...