A Fe-TAML/H2O2 catalytic oxidation process achieves facile in-solution total degradation of fenitrothion and two other organophosphorus (OP) pesticides. Degradation products have been identified and quantified providing evidence for oxidative hydrolysis, oxidative desulfuration, perhydrolysis, and deep oxidation. Degradation pathways can be selected by pH control to completely obviate all toxic...

background: the entrance of toxic compounds into wastewater treatment plants (wwtps) can induce disorder in their biological units. therefore, it is necessary to determine the sources of toxic wastewaters. in this study, the toxicity of the wastewater of 3 metal plating industries was assessed using sequencing batch reactor (sbr) bacteria. methods: to obtain the 1-1000 ml/l concentrations, the ...

Haematoxylum campechianum is a medicinal plant employed as an astringent to purify the blood and to treat stomach problems such as diarrhea and dysentery. A bio-guided chemical fractionation of the methanolic extract obtained from this plant allowed for the isolation of five compounds: two chalcones known as sappanchalcone (1); 3-deoxysappanchalcone (2); three homoisoflavonoids known as hematox...

During 3 years of a monitoring programme, 522 samples of fresh apples, six brands of fruit purées and various types of fruit baby food prepared from these materials were analysed. Each sample was examined for the presence of 86 GC amenable pesticide residues. The reporting limits of the procedure employed for sample analyses were in the range 0.003-0.01 mg kg(-1). Pesticide residues were detect...

The cotton aphid, Aphis gossypii Glover (Hemiptera Aphididae), is one of the most important sap sucking pests in many cotton-growing areas world-wide. In this study, the efficacies of seven insecticides [organophosphate (Fenitrothion & Pirimiphos-methyl), carbamate (Carbosulfan & Aldicarb), pyrethroid (Lambda-Cyhalothrin & Deltamethrin) and imidaclopride (Confidor)] were determined against four...

The presence of insecticide in the environment, due to extensive use in agriculture is of potential toxicological concern for fish. Histotoxicological studies have been widely used as biomarkes in the evaluation of the health of fish exposed to the pesticides studies. In the present study the hazardous effect of the organophosphate insecticide, Fenitrothion on the histology of the fresh water f...

Larvae of 26 strains of Aedes albopictus were tested for susceptibility to 5 organophosphate insecticides. The recently collected geographic strains included 13 from the USA, 5 from Brazil, 3 from Southeast Asia and 5 from Japan. The greatest amount of variability was seen among U.S. populations, ranging from quite susceptible to potentially resistant. Brazilian samples were generally quite sus...

Results ADP (EC50: 7.5 μM), ATP (EC50: 0.5 μM), UTP (EC50: 0.8 μM), and thio-UTP (EC50: 0.4 μM) increased the number of action potentials fired in response to current injection; UDP failed to affect action potential firing. The effect of ADP was attenuated by a P2Y1 antagonist. This enhancement of excitability was abolished by flupirtine (30 μM), a KV7 channel opener, and slightly, but insignif...