In this work, we have studied the antioxidant activity of fullerene C60 towards OH free radicals, using quantum chemistry and computational kinetics methods. Energy profiles are calculated using different basis sets, and reaction rate constants are reported for the first time. The reaction rate constant for the addition of the OH radical to the fullerene C60 is reported for the first time. A va...

The kinetic reaction of the benzofuran–stilbene hybrid compound 5-(2-(2-(4-hydroxyphenyl)benzofuran-5-yl)vinyl)benzene-1,3-diol captures HOO? free radical.

In free-radical polymerization, a monomer-initiator mixture is converted into a polymer. Depending on initial and boundary conditions, free-radical polymerization can occur either in a bulk mode (BP) or in a frontal mode (FP) via a propagating selfsustaining reaction front. The main goal of this paper is to study the role that bulk polymerization plays in frontal polymerization processes for va...

in this study, we measured the composition and free radical scavenging activity of several species of nuts, namely, torreya grandis, carya cathayensis,and myrica rubra. the nut kernels of the aforementioned species are rich in fatty acids, particularly in unsaturated fatty acids, and have 51% oil content. t. grandis and c. cathayensis are mostly produced in zhejiang province. the trace elements...

objective: recent studies have shown that the use of prolonged and intermittent normobaric hyperoxia (95%) decrease the infarct volume of stroke. the aim of current study was to study the effect of an oxygen radicals-scavenger applied during intermittent normobaric hyperoxia on infarct volume in the rat brain and neurologic deficit. materials and methods: male wistar rats (250-350 g) were divi...

background: brucella species can cause infection in a wide range of animals and human beings. oxidative events against brucella infection are not well elucidated. it is possible that brucellosis may be related to increased free radical production and antioxidant depletion. thus, the aim of this study was to determine the total antioxidant capacity (tac) before and after treatment of patients wi...

The mechanism of prostaglandin synthase-dependent (bi)sulfite (hydrated sulfur dioxide) oxidation was investigated using an enzyme preparation derived from ram seminal vesicles. The horseradish peroxidase-catalyzed oxidation of (bi)sulfite was used as a model system. Incubation of (bi)sulfite with prostaglandin synthase and arachidonic acid, 15-hydroperoxyarachidonic acid, or H2O2 results in th...

Uric acid has previously been shown to act as a water-soluble antioxidant. Although the antioxidant activity of uric acid has been attributed to its ability to scavenge free radicals, the one-electron uric acid oxidation product of such a scavenging reaction has not been detected. It order to determine whether a free radical metabolite of uric acid could be formed via one-electron redox process...

Ribonucleotide reductase (EC 1.17.4.1 -2) catalyses the direct reduction of ribonucleotides to the corresponding deoxyribonucleotides. This reaction enabled the evolution from the early ‘RNA world’ to the present ‘DNA world’. Storage of genetic information as DNA instead of RNA is much more stable and this was a prerequisite for the later development of multiple, separate, species [l] . Ribonuc...