Methane hydrate (MH) is a new energy resource in the 21 century. But the dissociation of MH from sediments during the MH exploration or oil/gas exploration under a hydrate layer accompanied by the softening of soils and formation of excess pore gas pressure may lead to ground failures and environmental disasters. In this study, experiments on modeling the weakening and failure of the sediment b...

Natural gas is projected to be the premium fuel of the 21st century because of availability, as well as economical and environmental considerations. Natural gas is coproduced with water from the subsurface forming gas hydrates. Hydrate formation may result in shutdown of onshore and offshore operations. Industry practice has been usage of alcohols--which have undesirable environmental impacts--...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

This paper reports the three-phase (gas + liquid + hydrate) equilibrium pressure versus temperature data for a (O3 + O2 + CO2 + H2O) system for developing the hydrate-based technology to preserve ozone, a chemically unstable substance, for various industrial, medical and consumer uses. These data cover the temperature range from 272 K to 277 K, corresponding to pressures from 1.6 MPa to 3.1 MPa...

We study diffusive transport of aqueous methane in sea sediments, which is important for formation of methane hydrate and gas deposits and has even been claimed to be principal methane transport mechanism for some geological systems. The isothermal diffusion law (Fick's law), D X = − ∇ J , which is employed in the literature for investigations on methane hydrate, is shown to significantly devia...

In this article, the effect of sodium dodecyl sulfate (SDS) as an anionic surfactant on the thermodynamics, formation rate, formation kinetic, critical micellar concentration (CMC) and stability of methane hydrate was studied. A CMC of SDS and water solution for methane hydrate formation conditions in a batch process was measured at 450 ppm, where CMC was determined by hydrate induction time. I...

Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the...

Neutron diffraction runs and gas-consumption experiments based on pressure-volume-temperature measurements are conducted to study the kinetics of methane hydrate formation from hydrogenated and deuterated ice powder samples in the temperature range of 245-270 K up to high degrees of transformation. An improved theory of the hydrate growth in a polydisperse ensemble of randomly packed ice sphere...

The thickness of the free gas column below the base of the gas hydrate stability zone is a proxy for the pore pressure in the free gas bearing sediments underneath. In the study area the pore over-pressrues derived under this assumption range between 0 and 1430 kPa ± 30% which appear to be the typical maximum over-pressure that the gas hydrate sediments can withstand before hydro-fracturing occ...