The efficiency of gas transport to the free and upper troposphere in convective clouds is investigated in an axisymmetric dynamic cloud model with detailed microphysics. In particular, we examine the sensitivity of gas transport to the treatment of gas uptake by different ice hydrometeors. Two parameters are used to describe this uptake. The 5 gas retention coefficient defines the fraction of d...

solute transport in unsaturated porous media can be viewed as a coupled phenomenon with waterand heat transport, together with mechanical behaviour of media. in this paper, solute transport is formulatedmathematically considering heat and water flow in deformable porous media. advection, dispersion anddiffusion of chemical species in the liquid phase are considered. convection and conduction fo...

The efficiency of gas transport to the free and upper troposphere in convective clouds is investigated in an axisymmetric dynamic cloud model with detailed microphysics. In particular, we examine the sensitivity of gas transport to the treatment of gas uptake by different ice hydrometeors. Two parameters are used to describe this uptake. The gas retention coefficient defines the fraction of dis...

To improve the feasibility of soil-aquifer remediation using bioaugmentation, more efficient methods are needed to widely disperse pollutant-degrading bacteria in porous media. Under water-saturated conditions, bacteria readily adhere to soil particles, but under unsaturated conditions, bacteria preferentially accumulate at the air-water interface. Air sparging a saturated porous medium produce...

An understanding of gas transport in unsaturated media is important for evaluation of soil aeration or movement of O 2 from the atmosphere to the soil. Soil aeration is critical for plant root growth because roots generally cannot get enough O 2 from leaves. Evaluation of gas movement is also important for estimating transport of volatile and semivolatile organic compounds from contaminated sit...

A novel approach of modeling gas-particle partitioning using polyparameter linear free energy relationships (ppLFERs) is implemented into three different multimedia box models (the OECD Pov and LRTP screening tool (The Tool), ChemRange, and CliMoChem) and compared to approaches based on the octanol-air partition coefficient (K(OA)). In all three multimedia models, calculated overall persistence...

The influence of sorption-induced coal matrix deformation on the evolution of porosity and permeability of fractured coal seams is evaluated, together with its influence on gas recovery rates. The porosity-based model considers factors such as the volume occupied by the free-phase gas, the volume occupied by the adsorbed phase gas, the deformation-induced pore volume change, and the sorptionind...

A tight [2]rotaxane with two chromophores as stoppers is described, in which the macrocycle is able to reversibly move by tuning of base. This moving process can result in intramolecular photo-induced electron transfer (PET), changing the photo-physical properties.