Pluronic poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (PEO-PPO-PEO) block copolymers are grafted with poly(vinyl pyrrolidone) by free radical polymerization of vinyl pyrrolidone with simultaneous chain transfer to the Pluronic in dioxane. This modified polymer has both thermal responsiveness and remarkable capacity to interact with a wide variety of hydrophilic and hydrop...

A novel polymeric sorbent has been synthesized by graft copolymerization of crosslinked polyvinyl alcohol with malic acid, and characterized by FTIR, TGA and swelling studies. A suitable and interesting method has been developed for the extraction and separation of lead ion with the graft copolymer. The lead ion uptake capacity of the polymer has been evaluated vis-a-vis varying pH and metal io...

0144-8617/$ see front matter 2010 Elsevier Ltd. A doi:10.1016/j.carbpol.2010.02.001 * Corresponding author. Tel.: +91 9005807357. E-mail address: [email protected] (K. Behari). The present paper reports the graft copolymerization of vinyl sulfonic acid onto sodium carboxymethyl cellulose by free radical polymerization using potassium peroxydiphosphate/thiourea redox system in an inert atmosp...

Extreme instability of pyrimidine motif triplex DNA at physiological pH severely limits its use for artificial control of gene expression in vivo. Stabilization of the pyrimidine motif triplex at physiological pH is therefore of great importance in improving its therapeutic potential. To this end, isothermal titration calorimetry interaction analysis system and electrophoretic mobility shift as...

Interactions between the graft copolymer poly(L-lysine)-g-poly(ethylene glycol), PLL-g-PEG, and two kinds of surface-supported lipidic systems (supported phospholipid bilayers and supported vesicular layers) were investigated by a combination of microscopic and spectroscopic techniques. It was found that the application of the copolymer to zwitterionic or negatively charged supported bilayers i...

Modification of natural polymers like protein by graft co-polymerization is an important method to incorporate the desired properties into the backbone. Soy protein concentrate (SPC) was grafted with ethylmethacrylate (EMA) using ascorbic acid /potassium persulphate as redox initiator system under pressure. Different reaction parameters such as reaction time, reaction pressure, solvent amount, ...

The post-functionalization of poly(3-hexylthiophene) (P3HT) via various synthetic routes is reported. Well-defined and monofunctionalized ω-thiol-terminated P3HT, ω-carboxylic acid-terminated P3HT, ω-acrylate-terminated P3HT, and ω-methacrylate-terminated P3HT are obtained in high yields through a straightforward procedure. From those, different novel P3HT-based graft copolymers are synthesized...

Gum polysaccharides are comprised of different monosaccharide units joined together by O-glycosidic linkages. The structural diversity of different polysaccharides is due to differences in degree of polymerization, monosaccharide composition, chain shapes, and linkage types. Gum polysaccharides are commonly used in both food and nonfood industries as stabilizers, thickening and gelling agents, ...