نتایج جستجو برای: high spin state
تعداد نتایج: 2856353 فیلتر نتایج به سال:
Iron complexes derived from 6-diaminotriazyl-2,2'-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.
The challenge motivating this paper is to induce, by chemical substitution, a silylyne, SiR, or a congeneric carbyne, CR, to adopt the high-spin quartet rather than the low-spin doublet as its ground state. The difficulty is seen in the preference for the doublet of the parent SiH (doublet-quartet energy difference ∼39 kcal/mol, favoring the doublet) or CH (∼17 kcal/mol). Strategies for having ...
In various statistical mechanical models, introduction of a metric into space of prameters gives a new perspective to the phase structure. In this paper, the scalar curvature R of this metric for a one dimensional four-state complex spin model is calculated. It is shown that this parameter has a similar behaviour to the Ising and Potts models.
blackberry diversity is high in iran due to its wild and natural populations especially in south of caspian sea. however it has not been investigated before. the goal of this work was to evaluate some wild populations of black berry in mazandaran province of iran. at first, region and then location of blackberries plants identified and the traits of leaf, stem, spin, flower, fruit quantity and ...
Two new mononuclear Fe(II) polymorphs, [(C2H5)4N]2[Fe(py3C-OEt)(NCS)3]2 (1) and [(C2H5)4N][Fe(py3C-OEt)(NCS)3] (2) (py3C-OEt = tris(pyridin-2-yl)ethoxymethane), have been synthesized characterized by single-crystal X-ray diffraction, magnetic photomagnetic measurements, detailed variable-temperature infrared spectroscopy. The molecular structure, in both complexes, is composed of the same anion...
Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-L(2,3) edge, we reveal that the spin state transition in LaCoO3 can be well described by a low-spin ground state and a triply degenerate high-spin first excited state. From the temperature dependence of the spectral line shapes, we find that LaCoO3 at finite temperatures is an inhomogeneous mixed-spin state syste...
In 1962, Overhauser showed that within Hartree-Fock (HF) the electron gas is unstable to a spin-density wave state. Determining the true HF ground state has remained a challenge. Using numerical calculations for finite systems and analytic techniques, we study the unrestricted HF ground state of the three-dimensional electron gas. At high density, we find broken spin symmetry states with a near...
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