We report the synthesis of a new kind of uniform hollow zeolite microspheres with hierarchical macro-/meso-/microporosity by an efficient strategy combining bi-templating, steam-assisted crystallization and then a mild alkaline etching method. This novel product has a hollow architecture, highly crystallized zeolite shells and more importantly, high dye adsorption capabilities.

Biopolymeric hollow nanospheres with stabilized structure have been prepared by self-assembly of amphiphatic photocrosslinkable carboxymethyl chitosans in a water medium into hollow nanocapsules and subsequent in situ photo-crosslinking of the photoreactive functional groups in the shells of the nanocapsules.

Gold (Au) nanoshells with solid silica cores have great potential for cancer photothermal therapy. However, this nanostructure cannot carry enough drugs. Here, we report a Au nanoshell with a hollow silica core for drug loading and cancer therapy. The silica shells were synthesized using nanoliposome templates, and then Au nanoshells were grown on the outer surface of the silica shells. Transmi...

Cubic shells and spherical nanoparticles of -SiC were produced at 1273 K by processing the ceramic precursors formed from the reactions between vapors of organochlorosilanes, Me2SiCl2, MeSiCl3, MeSiHCl2, and PhSiCl3, and liquid Na at 523-723 K. From Me2SiCl2, a flexible linear polycarbosilane precursor was synthesized and covered the NaCl byproduct surface to form a cubic shape. Hollow cubic -S...

A versatile method for the formation of monodisperse, bridged silsesquioxane nanoparticles with hollow interiors and porous shells has been developed using silica nanospheres as templates. Tunable size and shell thickness, as well as high surface areas and large pore volumes of the hollow particles, allow for practical application of these nanoparticles in many fields.

Hollow and tubular TpPa-COF structures have been synthesized by template-assisted replication of nanometer sized ZnO-nanorods. The hollow structures composed of microporous TpPa shells have high periodicity, moderate porosity, chemical stability and capsule shaped morphology as revealed by X-ray diffraction, porosity measurements, and SEM and TEM analyses.

In this paper the effect of random geometric imperfections on the critical load of isotropic, thin-walled, cylindrical shells under axial compression with rectangular cutouts is presented. Second moment characteristics of geometric imperfections are estimated by data of available measurements, a simulation procedure based on the Karhunen-Loève expansion is applied for generating realizations of...

In cylindrical continua, hoop stresses are induced due to the circumferential failure. This mainly happens when the cylinder is subjected to mechanical loads which vary in the circumferential directions. On the other hand, radial stress is stress in the direction of or opposite to the central axis of a cylindrical body. In the present study, the influence of curvilinear anisotropy on the radial...

Monodisperse hollow silica spheres of uniform size and ordered mesoporous shells have been successfully fabricated in water/heptane/CTAB nanoemulsions induced by compressed CO(2).

in this paper, simulation and analysis of thin steel cylindrical shells with elliptical cutouts under oblique loading were studied using finite element method. first, the numerical results were validated by the results of experimental test performed by an instron 8802 servo hydraulic machine. also, the effect of cutout angle (θ), cutout size, cutout position (l0/l) and cutout aspect ratios (b/a...