In this work, different ethyl 2,4-dioxo-4-arylbutanoate derivatives were prepared and evaluated for their Src Kinase inhibitory activity. For this purpose, the appropriate substituted acetophenone derivatives reacted with diethyl oxalate in the presence of sodium ethoxide in dried ethanol to give the corresponding products. All compounds showed moderate activities comparing with staurosporine a...

This review article covers the main types of gold(i) complexes used as precatalysts under homogeneous conditions in organic synthesis and discusses the different ways of catalyst activation as well as ligand, silver, and anion effects.

A divanadium-substituted phosphotungstate TBA(4)[γ-HPV(2)W(10)O(40)] (TBA = tetra-n-butylammonium) could act as an effective homogeneous catalyst for the H(2)O(2)-based oxidative bromination.

The tetraruthenium polyoxometalate water oxidation catalyst 1 performs very fast hole scavenging from photogenerated Ru(iii) polypyridine complexes, both in homogeneous solution and at a sensitized nanocrystalline TiO(2) surface.

A homogeneous carbene-based palladium catalyst was conjugated to a cell-penetrating peptide, allowing intracellular delivery of catalytically active Pd complexes that demonstrated bioorthogonal activation of a profluorophore within prostate cancer cells.

Synthesis of various potential biologically active compounds from the reaction of quinoline and vanillin based aldehydes and ethereal dialdehydes with indoles in the presence of RuCl3.nH2O as a homogeneous catalyst at room temperature is described.

In the present study, a heterogeneous and homogeneous gas flow dispersion model for simulation and optimization of a large-scale catalytic slurry reactor for the direct synthesis of dimethyl ether (DME) from synthesis gas (syngas) and CO2, using a churn-turbulent regime was developed. In the heterogeneous flow model, the gas phase was distributed into two bubble phases including small and large...

In this paper, an environmentally benign access to synthesize Bis(pyrazol-5-ol) derivatives was developed through the one pot pseudo five component condensation reaction of phenyl hydrazine with ethyl acetoacetate, and different aryl/heteroaryl aldehydes using morpholinium glycolate as the homogeneous reusable catalyst under solvent-free conditions at 80 °C. Further, the ionic liquid was prepar...

In this paper, an environmentally benign access to synthesize Bis(pyrazol-5-ol) derivatives was developed through the one pot pseudo five component condensation reaction of phenyl hydrazine with ethyl acetoacetate, and different aryl/heteroaryl aldehydes using morpholinium glycolate as the homogeneous reusable catalyst under solvent-free conditions at 80 °C. Further, the ionic liquid was prepar...

A series of cationic cobalt porphyrins was found to catalyze electrochemical water oxidation to O2 efficiently at room temperature in neutral aqueous solution. Co-5,10,15,20-tetrakis-(1,3-dimethylimidazolium-2-yl)porphyrin, with a highly electron-deficient meso-dimethylimidazolium porphyrin, was the most effective catalyst. The O2 formation rate was 170 nmol · cm(-2) · min(-1) (k(obs) = 1.4 × 1...