response surface methodology (rsm) was employed to determine the optimum processing conditions leading to maximum anthocyanin, phenolic compound and antioxidant activity during osmo-ultrasonic pretreatment followed by hot air drying of black cherry fruit. temperature (40, 50 and 60ºc), sucrose content (40, 50 and 60% w/v) and ultrasound frequency (0, 65 and 130 khz) were the factors investigate...

In the literature, iron-oxo complexes have been isolated and their hydrogen atom transfer (HAT) reactions have been studied in detail. Iron-imido complexes have been isolated more recently, and the community needs experimental evaluations of the mechanism of HAT from late-metal imido species. We report a mechanistic study of HAT by an isolable iron(III) imido complex, L(Me)FeNAd (L(Me) = bulky ...

Es wird von einem neuen [PCCP]Mo-Pincerkomplex mit koordinierten Alkin berichtet, der zur Spaltung molekularem Stickstoff eingesetzt wurde. Das, im Liganden fixierte η2-Alkin blieb während dieser Reduktion verschont. DFT-Rechnungen deuten darauf hin, dass die Reaktion über einen zunächst generierten terminalen N2-Komplex verläuft, dann in ein di-nukleares μ-(η1:η1)-N2-verbrücktes Intermediat üb...

In the title compound, C(24)H(12)BrF(2)NO(4), synthesized from 2-amino-3-bromo-1,4-naphthoquinone and 4-fluoro-benzoyl chloride, the two p-fluoro-phenyl rings are inclined at 73.9 (1) and 73.6 (1)° to the naphthoquinone ring system. The two imido carbonyl O atoms are anti to each other, while the fluoro-phenyl rings are located opposite each other, connected to the imide group in a funnel-like ...

Maleimides are often used for biomolecular conjugation with thiols. An underappreciated aspect of the imido group in a maleimide conjugate is its susceptibility to spontaneous hydrolysis, resulting in undesirable heterogeneity. Here, a chromophoric maleimide is used to demonstrate that both molybdate and chromate catalyze the hydrolysis of an imido group near neutral pH. Tungstate and 4-(dimeth...

The title compound, [Zr(C(5)H(5))(2)(C(4)H(9)N)(C(5)H(5)N)], was obtained from the reaction of (C(5)H(5))(2)Zr(py)(η(2)-Me(3)SiC(2)SiMe(3)) (py is pyridine) and (t)BuN=C=N(t)Bu alongside the formation of (C(5)H(5))(2)Zr(CN(t)Bu)(η(2)-Me(3)SiC(2)SiMe(3)). The zirconium atom is coordinated in a distorted tetra-hedral geometry by two cyclo-penta-dienyl ligands, a pyridine ligand, and a tert-butyl-...