A theoretical approach to consider formation of chemical compound layer at the interface between initial substances A and B due to the interfacial interaction and diffusion is developed. It is considered situation when speed of interfacial interaction is large enough and diffusion of A-atoms through AB-layer is much more then diffusion of B-atoms. Atoms from A-layer diffuse toward B-atoms and f...

An analytical model of the fluid/cell mechanical interaction was developed. The interfacial shear stress, due to the coupling between the fluid and the cell deformation, was characterized by a new dimensionless number N(fs). For N(fs) above a critical value, the fluid/cell interaction had a damping effect on the interfacial shear stress. Conversely, for N(fs) below this critical value, interfac...

Through coarse-grained molecular dynamics simulation, we aim to uncover the rupture mechanism of polymer-nanorod nanocomposites by characterizing the structural and dynamic changes during the tension process. We find that the strain at failure is corresponding to the coalescence of a single void into larger voids, namely the change of the free volume. And the minimum of the Van der Walls (VDWL)...

For interfacial interactions of “separable type” the existence is proved of stable multiphase equilibrium states minimizing the total energy which includes a sharp interface contribution along interfaces separating the phases. The second gradients of deformation do not occur; the theory is based on interfacial null lagrangians as determined in [11–12]. The interfacial interaction is always of s...

2014 We describe a method for the measurement of interfacial tensions in the millidyne/cm range by measuring the diffuse part of the total internally reflected light produced when the interfaces are illuminated close to the critical angle. This method has been used to measure the optimal interfacial tension in toluene-brine microemulsions in simultaneous equilibrium with the oil and aqueous pha...