We describe an unusual application of synchrotron energy-dispersive diffraction with hard X-rays to obtain structural information on metastable sodium sulfate heptahydrate. This hydrate was often mentioned in nineteenth and early twentieth century scientific literature but rarely in modern publications, and it had not been characterised structurally. Using a unique three-detector fixed-angle X-...

A Raman spectrometer extensively modified for deep ocean use was used to measure synthetic hydrates formed in an ocean environment. This was the first time hydrates formed in the ocean have been measured in situ using Raman spectroscopy. Gas hydrates were formed in situ in the Monterey Bay by pressurizing a Pyrex cell with various gas mixtures. Raman spectra were obtained for sI methane hydrate...

The chemical speciation of arsenic in sediments and porewaters of aquifers is the critical factor that determines whether dissolved arsenic accumulates to potentially toxic levels. Sequestration of arsenic in solid phases, which may occur by adsorption or precipitation processes, controls dissolved concentrations. We present synchrotron x-ray absorption spectra of arsenic in shallow aquifer sed...

Background and Objectives: In the original in vitro method for evaluation of iron bioavailability using caco-2 cell model, ferritin formation by cells is considered as a functional indicator of both absorption and utilization of iron. However, as iron is measured in the tested material and then ferritin concentration is measured in caco-2 cell lysate, it is almost impossible to have a concrete ...

OBJECTIVES To compare the safety and efficacy of iron carboxymaltose with ferrous sulfate to treat iron deficiency anemia in the post partum. METHODS Patients were randomized (2:1 ratio) to receive iron carboxymaltose (up to 3 weekly doses of 1000 mg maximum, applied in 15 min; n=227) or ferrous sulfate (100 mg twice daily, 12 weeks; n=117). Changes in hemoglobin and iron stores up to week 12...

Introduction: The Mars Exploration Rover (MER) missions have stimulated considerable thinking about the surficial geochemical evolution of Mars [1-4]. Among the major MER findings is the presence of the mineral, jarosite (a ferric sulfate salt), which suggests formation from an acid-sulfate brine. The objectives of this work were to (1) add ferric iron chemistry to an existing ferrous iron mode...

background and objectives: in the original in vitro method for evaluation of iron bioavailability using caco-2 cell model, ferritin formation by cells is considered as a functional indicator of both absorption and utilization of iron. however, as iron is measured in the tested material and then ferritin concentration is measured in caco-2 cell lysate, it is almost impossible to have a concrete ...

BACKGROUND Recent studies in humans suggest that ferritin iron in soybeans has high bioavailability. However, direct evidence for this is lacking because the soybeans were intrinsically labeled; thus, iron bound to other ligands, such as phytate, was also labeled. OBJECTIVE The objectives of the study were to evaluate the absorption of iron from extrinsically labeled, purified ferritin (horse...

Recoil-free emission of 14.37 keV lines by iron atoms undergoing radioactive decay can be exploited in high-resolution Mössbauer spectroscopy thanks to the long lifetime of the excited state. This experiment determined the natural energy width of the Mössbauer 14.37 keV line to be (1.36 ± 0.24)· 10−12 keV, giving a relative width of around 10−13. Another application of this experiment was in ch...