نتایج جستجو برای: isomorphous substitution
تعداد نتایج: 57056 فیلتر نتایج به سال:
Elevated antimony concentrations in aqueous environments from anthropogenic sources 9 is becoming of global concern, here iron oxides are known to strongly adsorb aqueous antimony 10 species with different oxidation states, but the effect of silica on the removal characteristics is not 11 well understood despite being a common component in the environment. In this study, ferrihydrite 12 was syn...
A direct-methods procedure has been proposed for separating the phase doublet resulting from the use of either isomorphous replacement or anomalous scattering techniques. The phase doublet is expressed as ~#u= ~h±lA~.l. Formulae combining the structure-factor relationships with the phase-doublet information are given. Problems concerning the practical applications are also discussed. A test cal...
BACKGROUND Ribosomes are the universal cellular organelles that accomplish the translation of the genetic code into proteins. Electron cryo-microscopy (cryo-EM) has yielded fairly detailed three-dimensional reconstructions of ribosomes. These were used to assist in the determination of higher resolution structures by X-ray crystallography. RESULTS Molecular replacement studies using cryo-EM r...
Advances in beamline optics, detectors and X-ray sources allow new techniques of crystallographic data collection. In serial crystallography, a large number of partial datasets from crystals of small volume are measured. Merging of datasets from different crystals in order to enhance data completeness and accuracy is only valid if the crystals are isomorphous, i.e. sufficiently similar in cell ...
and refinement was usually complete after ten to fifteen cycles. The refined values of the parameters compared well with the Rossmann programme values, except for the effective atomic numbers, which were uniformly smaller than indicated by the Rossmann programme. The Hart hO1 values were used in the 2 /~. Fourier synthesis, although there may be some question remaining about the proper Z values...
Three 2D and 3D photoreactive MOFs of trans,trans-muconic acid with Er(3+) and their corresponding isomorphous Y(3+) phases were synthesized and their photoreactivity was studied as a function of the crystal environment.
The title compound, C(18)H(15)BrSi, crystallizes with two almost identical mol-ecules (r.m.s. deviation for all non-H atoms = 0.074 Å) in the asymmetric unit. It is isomorphous with chloro-triphenyl-silane.
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