A simple identification method of L-tyrosine (Tyr) and L-cysteine (Cys) using gemini surfactant coated CdSe quantum dots by using a fluorescent spectroscopic technique is proposed. The gemini surfactant modified QDs show a selective fluorescence response between Tyr and Cys by addition of p-sulfonatocalix[4]arene (pSCA). The CdSe QDs coated with gemini surfactant [C(12)H(25)N(+)(CH(3))(2)(CH(2)...

Cross-linked metal-imprinted chitosan microparticles were prepared from chitosan, using four metals (Cu(II), Zn(II), Ni(II), and Pb(II)) as templates, and epichlorohydrin as the cross-linker. The microparticles were characterized by Fourier transform infrared spectroscopy, solid state (13)C nuclear magnetic resonance spectroscopy, and energy-dispersive X-ray spectroscopy. They were used for com...

A simple kinetic model for the enzymatic activity of surface-active proteins against mixed micelles has been developed. This model uses the Langmuir adsorption isotherm, the classic equation for the binding of gas molecules to metal surfaces, to characterize enzyme adsorption to micelles. The number of available enzyme binding sites is equated with the number of substrate and inhibitor molecule...

Removal of Basic Violet 10 (BV-10) from aqueous solution by adsorption on used black tea leaves (UBTL) was studied in batch process. The effects of contact time, pH, concentration and temperature, etc. on adsorption have been investigated. The UV-visible spectrophotometric method was used to analyze BV-10 in solution at constant pH. From the optimization of solution pH, equilibrium adsorption e...

A sensitivity analysis was performed on a sediment-phosphate transport model by determining the phosphate sorption characteristics of separated size fractions and prepared size distributions of fine-grained ( < 64 jum) river sediment typically transported in two southern Ontario streams. The Langmuir equation was used to quantify phosphate release from the sediment. Results of the study indicat...

A carbonaceous adsorbent (TPC) prepared from Thespusia populinia bark by acid treatment was tested for its efficiency in removing Rhodamine B (RDB). The parameters studied include agitation time, initial dye concentration, carbon dose, pH and temperature. The adsorption followed first order reaction equation and the rate is mainly controlled by intra-particle diffusion. Freundlich and Langmuir ...

Sesame leaf, an agricultural solid waste, was used as low cost adsorbent for removal of Pb(II) from aqueous solution in batch mode. The biosorbent was characterized by thermo-gravimetric analysis and Fourier transform infrared spectroscopy. The influences of phase contact time, solution pH, adsorbent dosage, and initial concentrations were investigated to optimize the conditions for maximum ads...

Removal thermodynamics and desorption studies of some heavy metal ions such as Co(II), Cu(II) and Pb(II) by polymeric surfaces such as poly 2-hydroxyethyl methacrylate (PHEMA) and copolymer 2-hydroxyethyl methacrylate with monomer methyl methacrylate P(MMA-HEMA) as adsorbent surfaces from aqueous single solution were investigated with respect to the changes in pH of solution, adsorbent composit...

The Sips isotherm equation, proposed in 1948, is popularly used to describe the adsorption of a diverse array water contaminants by engineered and natural adsorbents. However, that apparent popularity conceals problematic application issues. Our critique its use contaminant research threefold. First, we show linear version equation promoted several reviews bogus. We also highlight problems asso...