Previously reported ion-specific equation coefficients for both the Abraham general solvation model and Goss modified Abraham model are updated using recently measured activity coefficient, gas chromatographic retention factor, and solubility data for solutes dissolved in room temperature ionic liquids (RTILs). Reported for the first time are equation coefficients for 1-propyl-2,3-dimethylimida...

this paper is mainly focusing on the determination of mean molal activity coefficient of hcl in aqueous acidic medium. the present investigations have been carried out to determine the activity coefficients of hydrochloric acid in 2-propanol water mixture solutions under various conditions to study the ion solvent interactions in different temperatures. the standard molar potential em0 of the c...

the magnetically recoverable fe3o4 nanoparticle and the supported brønsted acidic ionic liquid 1-methyl-3-(3-trimethoxysilylpropyl) imidazolium hydrogen sulfate (fe3o4-il-hso4) were synthesized and used as efficient magnetic catalysts for the regioselective thiocyanation of aromatic and heteroaromatic compounds at room temperature in water: ethanol. this procedure provided the target thiocyanat...

The effect of pH, ionic strength, and cation in solution on the binding of phenanthrene by a soil humic acid in the aqueous phase was determined using fluorescence quenching. The phenanthrene binding coefficient with the dissolved soil humic, Koc, decreased with increasing ionic strength and solution cation valence. At low values of ionic strength, Koc values for this soil humic acid increased ...

In an attempt to develop predictive tools for the determination of new ionic liquid solvents, QSPR models for the melting points of 126 structurally diverse pyridinium bromides in the temperature range 30-200 degrees C were developed with the CODESSA program. Six- and two-descriptor equations with squared correlation coefficients (R(2)) of 0.788 and 0.713, respectively, are reported for the mel...

In order to predict the variations of the channel ionic resistance with time, we follow the framework proposed by Taylor and Aris to analyze our results. We consider here a channel of radius R, length L, and the diffusion coefficient of the salt in the solution is D. Solving the Navier-Stokes equation for a cylindrical channel, under the assumption of no-slip boundary condition, the velocity pr...

A report is presented on the use of cyclic voltammetry using silver as a working electrode. The combined electrocatalytic properties of silver and ionic liquids allow cyclic voltammetry to be turned into an ideal tool for the rapid and accurate access to diffusion coefficient values and solubility values of carbon dioxide in ionic liquids under standard conditions.