We use the thermodynamic model introduced by Aptekar’ and Ponyatovskiy for the – transformation in cerium metal to study the properties f plutonium metal. The model describes the – transformation in Pu and explains the minimum in the melting versus pressure curves for both aterials. Ga stabilization of the -phase of Pu is explained in terms of a first order transition between the two phases. Th...

The thiosemicarbazone of 9-anthraldehyde, (9-ATSC) and its group 12 metal complexes have been synthesized. The four compounds have been characterized by IR, electronic and NMR spectrometries, molar conductivity, melting points and elemental analysis. In all the complexes, the 9-ATSC coordinates through the sulfur and the azomethinic nitrogen. The zinc (II) complex shows a 1:2 metal to ligand st...

The imidazole-Ag(I)-imidazole base pair is one of the best-investigated artificial metal-mediated base pairs. We show here that its stability can be further improved by formally replacing the imidazole moiety by a 2-methylimidazole or 4-methylimidazole moiety. A comparison of the thermal stability of several double helices shows that the addition of one equivalent of Ag(I) leads to a 50% larger...