A radio-frequency (RF) helicon plasma reaction chamber (HPRC) is developed and used to decompose methane gas into high-purity hydrogen gas and solid carbon in the form of graphite. A single-turn (m = 0) helicon antenna, operated at 13.56 MHz, and a 100 G dipole magnetic field are used to excite a helicon mode in a nonthermal plasma, creating plasma densities exceeding 1013 cm−3 using 8–20 SCCM ...

Rapid cupric oxide quantum dot (CuO QDs) synthesis through plasma–ethanol non-equilibrium electrochemistry process.

We illustrate how the Jarzynski equality (JE), which is the progenitor of non-equilibrium methods aimed at constructing free energy landscapes for molecular-sized fluctuating systems subjected to steered transformations, can be applied to derive equations of state for bulk systems. The key-step consists of physically framing the computational strategy of "total energy morphing", recently presen...

In this study the enthalpies of dissociation for pure methane and pure carbon dioxide was calculated using a hydrate equilibrium data obtained in this study. The enthalpy of dissociation was determined using Clausius-Clapeyron equation. The results were compared with the values reported in literature obtained using various techniques. Keywords—Enthalpies of dissociation, methane, carbon dioxide...

Recent experimental evidence suggests again the existence of the metastable methane anion in plasma swarms. In order to test the reliability of the complete basis set (CBS) extrapolation scheme with augmented correlation-consistent basis sets for anionic molecules, we study the evolution of the electron affinity of methane with benchmark ab initio calculations with aug-cc basis sets up to aug-c...