A new gallium based metal-organic framework, denoted as Ga-MIL-53-FcDC, with the chemical formula [Ga(OH)(FeC12H8O4)] was synthesized using ferrocene containing linker molecule 1,1’-ferrocenedicarboxylic acid (H2FcDC, FeC12H10O4). The porous nature of compound could be confirmed by nitrogen sorption and a specific surface area 270 m2/g determined. persistence complex inside structure Mössbauer-...

The presence of bisphenol A (BPA) in wastewater, its toxicity and the hardness for complete degradation constitutes a serious environmental problem scientific challenge. enzyme laccase is an oxidoreductase capable oxidizing phenolic compounds, being one most efficient biocatalysts BPA removal. immobilization laccases to lead solid essential their applications as it allows stabilization easy rec...

In recent years, environmental pollution has become more serious, especially the organic pollutants. Metal frameworks (MOFs) are promising materials used to degrade pollutants recently. Among them, Materials Institute Lavoisier (MILs) have been widely engaged due their good stability and unique structural characteristics. This paper systematically analyses summarizes progress of MILs in degrada...

Metal-organic framework composites, which are combined from metal-organic and advanced carbon material, have drawn great attention in many fields of application such as environmental remediation catalysts. Within this paper, the carbon/MIL-53(Fe) composite was fabricated via an situ synthesis, N-containing dots (NCDs) were mixed with MOF precursors’ solutions under various ratios before going t...

Aluminum aminoterephthalate MOF particulate materials (NH(2)-MIL-101(Al) and NH(2)-MIL-53(Al)), studied here as components of self-detoxifying surfaces, retained their reactivity following their covalent attachment to protective surfaces utilizing a newly developed strategy in which the MOF particles were deposited on a reactive adhesive composed of polyisobutylene/toluene diisocyanate (PIB/TDI...

A new class of microporous adsorbents, the metal-organic frameworks was recently developed. Despite their promising characteristics, not much is known about their adsorption behaviour, certainly for mixtures. In this work, vapour and gas phase adsorption and separation of (i) linear and branched alkanes, cyclohexane and benzene, (ii) C8 alkylaromatic compounds and (iii) CO2 and CH4 is studied o...