Layered molybdenum disulfide has demonstrated great promise as a low-cost alternative to platinum-based catalysts for electrochemical hydrogen production from water. Research effort on this material has focused mainly on synthesizing highly nanostructured molybdenum disulfide that allows the exposure of a large fraction of active edge sites. Here we report a promising microwave-assisted strateg...

Determination of molybdenum(VI) by direct spectrophotometry and simultaneous determination of molybdenum(VI) and titanium(IV) are reported. Molybdenum(VI) gives a golden yellow colour with 2,4dihydroxybenzaldehyde isonicotinoyl hydrazone with a 1:2 metal-reagent stoichiometry at pH 1.5. The complex shows an absorption maximum at 445 nm with molar absorptivity and Sandell's sensitivity of 1.02x1...

The use of N-hydroxy-N-p-chlorophenyl-N'-(2-methyl-4-chlorophenyl)benzamidine hydrochloride abbreviated as HCPMCPBH as a highly selective chelating agent for molybdenum has been investigated. The dioxomolybdenum complex Mo02(C20H1 5N20Ch)2 is quantitatively precipitated at pH = 2.8-6.6. As the complex can not be washed free of excess reagent, the dried complex is ignited at 500-550 °c to Mo03 f...

Molybdenum disulfide, a type of two-dimensional layered material with unique properties, has been widely used in many fields. However, an exact understanding of its toxicity remains elusive, let alone its effects on the environmental microbial community. In this study, we utilized metabolomics technology to explore the effects of different concentrations of molybdenum disulfide nanosheets on Es...

An active Neurospora-like assimilatory NADPH-nitrate reductase (EC 1.6.6.2), which can be formed in vitro by incubation of extracts of nitrate-induced Neurospora crassa mutant nit-1 with extracts of (a) certain other nonallelic nitrate reductase mutants, (b) uninduced wild type, or (c) xanthine oxidizing and liver aldehyde-oxidase systems was also formed by combination of the nit-1 extract with...

Oxide Dispersion Strengthened (ODS) and TZM molybdenum have excellent creep resistance and strength at high temperatures in inert atmospheres. Fracture toughness and tensile testing was performed at temperatures between -1 50°C and 450°C to characterize 6.35 mm thick plate material of ODS and TZM molybdenum. A transition from low fracture toughness values (5.8 to 29.6 MPaJm) to values > 30 MPaJ...

Sulfite oxidase (EC 1.8.3.1), when reduced by sulfite, exhibited the electron paramagnetic resonance spectrum of molybdenum(V). Specific calorimetric analyses demonstrated that the purified enzyme contained 1 molybdenum per heme. The electron paramagnetic resonance signal of molybdenum, which was generated by the addition of sulfite, was enriched by the purification procedure to the same degree...

A hydroponic trial was carried out to investigate the effect of molybdenum (Mo) on uptake of phosphorus (P) in different rice cultivars. The experiment was conducted using a randomized complete-block design, with a split-plot arrangement of treatments and three replications. Four rates of Mo (0, 0.01, 0.1 and 1 mg L) and five cultivars (MR219, HASHEMI, MR232, FAJRE and MR253) provided the main ...

Establishing processing-structure-property relationships for monolayer materials is crucial for a range of applications spanning optics, catalysis, electronics and energy. Presently, for molybdenum disulfide, a promising catalyst for artificial photosynthesis, considerable debate surrounds the structure/property relationships of its various allotropes. Here we unambiguously solve the structure ...