Cu-exchanged aluminosilicate zeolites have been intensively studied for the selective oxidation of methane to methanol via a chemical looping manner, while nature active Cu-oxo species these catalysts is still under debate. This study inquired into effects Al distribution on over zeolites, which provided an effective way discern activity difference between mononuclear and polynuclear species. S...

Cu-Exchanged zeolites are known as active materials for methane oxidation to methanol. However, understanding of the formation of Cu active species during synthesis, dehydration and activation is fragmented and rudimentary. We show here how a synthesis protocol guided by insight in the ion exchange elementary steps leads to highly uniform Cu species in mordenite (MOR).

We have investigated various silica zeolites using density functional theory with periodic supercells, plane waves, and pseudopotentials. These zeolitic phases include silica sodalite, chabazite, mordenite, silica LTA, and silicalite. Atom-level geometries, elastic properties, and cohesive energies are presented. Although the zeolites exhibit a wide range of Si-O-Si angles and densities, the co...

supported catalysts synthesized via the interaction of mg(oet)2 with ticl4 in the presence or absence of an internal stereoregulating donor (di-n-butyl phthalate), with different solvents (chlorobenzene, n-undecane, n-heptane) at different titanation temperatures have been studied by a set of physicochemical methods. data on the chemical composition, x-ray structure and pore structure of these ...

quantitative determination of br?nsted acid sites in acidic mordenite samples with varying proton concentrations has been studied using aqueous conductometric titration method. conductometric titration of the ammonium form of mordenite with sodium hydroxide is feasible and the results indicate potential number of br?nsted acid sites. however, br?nsted acid sites concentration in acidic mordenit...