in this paper, the chemical functionalization of carboxylated multi-walled carbon nanotubes (mwnt-cooh) by 1,2-phenylenediamine, have been investigated. mwnt-benzimidazole is obtained through mwnt-amide reaction with pocl3 after 72h, which is confirmed by ft-ir, sem, tga, and elemental analysis. these functionalizations have been chosen due to –nh2 and nhco active sites in mwnt-amide for future...

Vertically aligned single-walled carbon nanotubes (VA-SWNTs) have been synthesized by an Alactivated plasma-enhanced chemical vapor deposition (PECVD) method. On this basis, we have developed a facile but effective method for direct growth of multicomponent micropatterns of VA-SWNTs interposed within the patterned areas surrounded by vertically aligned multi-walled carbon nanotubes (VA-MWNTs) o...

We report a simple but powerful method for engineering multi-walled carbon nanotubes (MWNTs) by using manipulation by an atomic-force microscope. The successive shell-by-shell extraction process of ultralong MWNTs allows the exposure of the innermost single-walled carbon nanotubes (SWNTs), which have diameters as small as approximately 0.4 nm. The inner-shell extraction process changes the elec...

BACKGROUND Different types of carbon nanotubes may represent toxic hazards due to their size distribution and massive surface area. They may adsorb other toxic agents that can consequently be transported into the body. Hence the aim of this study was to confirm or reject the hypothesis of carcinogenicity of two types of carbon nanotubes. MATERIALS AND METHODS Well-defined single-walled and mu...

In contrast to our previous study (Barth & Marx, 2008) dealing with a currently decreasing research field (high-temperature superconductors) we analyzed here a topic which has raised a strongly increasing interest among researchers: research activities around carbon nanotubes (CNTs or NTs). Carbon nanotubes (often named only nanotubes) are graphite sheets rolled up into cylinders with diameters...

in the present study, ptruce/mwnts nanocatalysts synthesized via polyol process technique are applied as anode electro-catalyst in methanol electro-oxidation reaction (mor). to characterize the nanocatalysts, tem, xrd, eds and xps are investigated. cyclic voltammetry and choronoamperometry are used to evaluate the electro-catalytic activity and stability of the catalysts in methanol electro-oxi...

multi-walled carbon nanotubes (mwnt’s) were synthesized using chemical vapor deposition (cvd) method in a fluidized bed reactor under the flow of methane and hydrogen gases. a cobalt-molybdenum/magnesium oxide (co-mo/mgo) nanocatalyst was used as the catalyst of the process. the samples were analyzed using scanning electron microscopy (sem) and x-ray diffraction (xrd) analyses. the effects of d...

Here we report on the ion conductance through individual, small diameter single-walled carbon nanotubes. We find that they are mimics of ion channels found in natural systems. We explore the factors governing the ion selectivity and permeation through single-walled carbon nanotubes by considering an electrostatic mechanism built around a simplified version of the Gouy-Chapman theory. We find th...

single-walled carbon nanotubes (swcnt) and multi-walled carbon nanotubes(mwcnt) were melt-blended with polyvinylidene fluoride (pvdf).ft-ir technique revealed that swcnt has insignificant effect on the crystalline structure of pvdf and at 3wt% modification only 14% beta crystal isformed. this observation was accounted for by the chair structure of swcnt. in mwcnt nancomposites it was found that...

Double-walled TiO2 nanotubes with porous wall morphologies are fabricated by anodization under ultraviolet (UV) irradiation. TiO2 formed by anodization of Ti is activated to generate electrons and holes by UV and the anodization process is influenced by the photo-generated charges. As a consequence, morphologies of the fabricated TiO2 nanotubes can be adjusted by controlling the UV illumination...