نتایج جستجو برای: n heterocyclic
تعداد نتایج: 981942 فیلتر نتایج به سال:
An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHCwith heavier group 14 elements. Three novel compounds (NHC)2 SiCl2H2 (2), aNHC SiCl2H2 (3), and aNHC GeCl2 (4) have been synthesized and characterized by single crystal X-ray analys...
An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)(2)·SiCl(2)H(2) (2), aNHC·SiCl(2)H(2) (3), and aNHC·GeCl(2) (4) have been synthesized and characterized by single crystal...
2-Phosphanyl-substituted imidazolium salts 2-PR2(4,5-Cl-Im)[OTf] (9a,b[OTf]) (4,5-Cl-Im = 4,5-dichloro-1,3-bis(2,6-di-isopropylphenyl)-imidazolium) (a: R = Cy, b: R = Ph) are prepared from the reaction of R2PCl (R = Cy, Ph) with NHC 8 (4,5-dichloro-1,3-bis(2,6-di-isopropylphenyl)-imidazolin-2-ylidene) in the presence of Me3SiOTf. 5-Phospanyl-substituted imidazolium salts 5-PR2(2,4-Cl-Im)[OTf] (...
The synthesis of the first four-membered N-heterocyclic carbene is described. Depending on the substituents on the nitrogen atoms, it is possible to characterize at room temperature the carbene dimer or the free carbene. Crystallographic analyses are provided for these carbene species.
Aza-Michael addition of amines, including aromatic and aliphatic amines, with α, β-unsaturated ketones was realized employing N-Heterocyclic Carbene (NHC) as organocatalyst, yielding β-amino ketones with up to 98% yield.
The new phosphaalkenyl(chloro)tin(II) compound NHC-Sn(Cl)[C(SiMe3)=PMes*] was isolated and fully characterized including molecular structure determination by a single crystal X-ray diffraction analysis. Its reaction with Me2SAuCl led to the formation of an unprecedented P=C-bridged trinuclear gold complex [AuC(SiMe3)=PMes*]3 through the transfer of the phosphaalkenyl substituent to the gold atom.
The title compound, C(14)H(16)N(4)O(2)S, is a Schiff base derivative of 2-(methyl-sulfan-yl)benzaldehyde. The configuration about the C=N double bond is E. The heterocyclic ring is essentially planar (τ = 3.1°) and makes a dihedral angle of 12.24 (7)° with the benzene ring. An intra-molecular N-H⋯S hydrogen bond is observed. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds link mol-ecules into la...
Magnesium dications bind strongly to a tridentate anionic dicarbene ligand L = [N{CH(2)CH(2)(CNCHCHNMes)}(2)] forming dinuclear and trinuclear Mg complexes with some particularly short Mg-C bonds. Treatment of the proligand H(4)LCl(3) with three equivalents of methyl magnesium chloride or benzyl magnesium chloride affords Mg(3)(HL)Cl(6) in high yield. A suspension of in thf was heated to 80 deg...
N-Heterocyclic carbenes, or NHCs as they are commonly abbreviated, have attracted significant interest over the past decade due to their widespread utility in chemical transformations. As ligands on transition metals, NHCs have been found to have properties similar to those of the widely employed phosphine ligand, due to their ability to act as both a Lewis base and a Lewis acid at the same tim...
Conjugate acids of cyclic (amino)(phosphino)carbenes (P-NHCs) have been prepared, and several different processes have been observed during their deprotonation, which include the formation of a metastable P-NHC, an azomethine ylide, and a bicyclic phosphirane.
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