By using the substituent effect to tune the palladium(II)-involved reactivity, a new probe is found to respond quantitatively to Pd(II). Unexpectedly, the probe gave an emission band in the desirable near-infrared (NIR) region (780 nm), thus providing the first NIR sensor for palladium detection.

Near-infrared (NIR) spectroscopy in diffuse reflectance mode was explored with the objective of discriminating sea salts according to their quality type (traditional salt vs "flower of salt") and geographical origin (Atlantic vs Mediterranean). Sea salts were also analyzed in terms of Ca(2+), Mg(2+), K(+), alkalinity, and sulfate concentrations to support spectroscopic results. High concentrati...

Infrared thermography is becoming ever more popular in civil engineering/architecture mainly due to its noncontact character which includes two great advantages. On one side, it prevents the object, under inspection, from any alteration and this is worthwhile especially in the presence of precious works of art. On the other side, the personnel operate in a remote manner far away from any hazard...

Recently, the study of near- and below- threshold regime harmonics as a potential source of intense coherent vacuum-ultraviolet radiation has received considerable attention. However, the dynamical origin of these lower harmonics, particularly for the molecular systems, is less understood and largely unexplored. Here we perform the first fully ab initio and high precision 3D quantum study of th...

near infrared spectroscopy Jan Mehnert1,2, Christoph Schmitz1,3, Harald E. Möller2, Arno Villringer1,2,4,5, Hellmuth Obrig1,2,5 and Karsten Müller2 1Berlin NeuroImaging Center, Charité University Hospital Berlin, Germany/2MaxPlanck Institute for Human Cognitive and Brain Sciences Leipzig, Germany/3NIRx Medizintechnik GmbH, Berlin, Germany/4Berlin School of Mind and Brain, Humboldt University Be...

We describe a static aperture-coded, dispersive longwave infrared (LWIR) spectrometer that uses a microbolometer array at the detector plane. The two-dimensional aperture code is based on a row-doubled Hadamard mask with transmissive and opaque openings. The independent column code nature of the matrix makes for a mathematically well-defined pattern that spatially and spectrally maps the source...

The rotationally resolved infrared spectrum of the hydrogen bonded complex H(2)S-HF and of its isotopomer D(2)S-DF in the HF/DF stretching range have been observed in a supersonic jet Fourier-transform infrared (FTIR) experiment and indicate a predissociation lifetime of 130 ps for H(2)S-HF. Complementary spectra taken at a temperature of 190 K in a cell without resolved rotational structure in...

We review the evidence which suggests that ultraluminous infrared galaxies (ULIGs) are the precursors of optically selected quasi-stellar objects (QSOs) and discuss additional data that suggests that the majority, if not all QSOs, may begin their lives in an intense infrared phase. Implications for the host galaxies of QSOs are discussed.