Ammonia (NH3) emission from animal feeding operations (AFOs) has caused concerns on public health and environmental degradation, such as ecosystem acidification, eutrophication, and formation of PM2.5 fine particles. Current ammonia emission measurement methodologies are accurate and reliable, but time consuming, expensive, and impractical for most facilities. In the present study, an alternati...

The reduction of ammonia (NH3) emissions is urgently needed due to its role in aerosol nucleation and growth causing haze formation during its conversion into ammonium (NH4(+)). However, the relative contributions of individual NH3 sources are unclear, and debate remains over whether agricultural emissions dominate atmospheric NH3 in urban areas. Based on the chemical and isotopic measurements ...

Ammonium (NH4(+)) migration across a cation exchange membrane is commonly observed during the operation of bioelectrochemical systems (BES). This often leads to anolyte acidification (pH <5.5) and complete inactivation of biofilm electroactivity. Without using conventional pH controls (dosage of alkali or pH buffers), the present study revealed that anodic biofilm activity (current) could be su...

Based on hydrogen bonding, the highly uniform polyaniline (PANI) nanotubes were synthesized by self-assembly method using citric acid (CA) as the dopant and the structure-directing agent by optimizing the molar ratio of CA to aniline monomer (Ani). Synthesis conditions like reaction temperature and mechanical stirring were considered to explore the effects of hydrogen bonding on the morphologie...

Limited availability of ammonia (NH3) observations is currently a barrier for effective monitoring of the nitrogen cycle. It prevents a full understanding of the atmospheric processes in which this trace gas is involved and therefore impedes determining its related budgets. Since the end of 2007, the Infrared Atmospheric Sounding Interferometer (IASI) satellite has been observing NH3 from space...

In this study the interaction of cis-PtCl2(NH3)2 complex and graphene were investigated with MPW1PW91method in gas and solvent phases. The solvent effect was examined by the self-consistent reaction fieldtheory (SCRF) based on Polarizable Continuum Model (PCM). The selected solvents were chloroform,chlorobenzene, bromoethane, dimethyldisulfide, and dichloroethane. The solvent ...

The objective of this study was to examine ammonia (NH3) exhaust emissions as a function of different vehicle operating conditions and cycles. A total of eight vehicles with low-emission vehicle (LEV) to super-ultra-low-emission vehicle (SULEV) certification were tested over the Federal Test Procedure (FTP75), a US06 cycle, a hot running 505, a New York City Cycle (NYCC), and a specially design...

We present high angular resolution observations of the NH3(1,1), (2,2) and (3,3) inversion transitions from the Egg Nebula, the archetypical proto-planetary nebula. The spatial distribution and kinematics of the emission in all three lines show four distinct components or lobes that are aligned with the polar and equatorial directions. The kinematics of the NH3 emission is also found to follow ...

This study was conducted on soybean (Glycine max L. Merr.) nodules to determine if exogenous NH3 exerts a controlling influence over nitrogenase activity through changes in nodule gas permeability (P), and if decreasing carbohydrate availability, as a result of low-light treatment, increases the sensitivity of root nodules to NH3. Nodulated root systems of intact plants were exposed to one of s...

The adsorption of a model nerve agent, O,S-dimethyl methylphosphonothiolate (DMPT), on the hydroxylated and unhydroxylated nano-crystalline magnesium oxide surface followed by the nucleophilic attack of ammonia (NH3) is investigated at the M06-2X/6-311++G(d,p) level of theory using the representative cluster models. The geometries of DMPT and NH3 are fully optimized, while the geometry of the o...