[Ni3(C2H3 0 2 )2(CH3 0 H)2L2] [L = l,3-bis(5-chlorosalicylideneamino)propan-2-ol dianion, (C2H3 0 2 )_ = acetate, (CH3OH) = methanol] was synthesized and its crystal structure was determined. It crystallizes in the monoclinic spaceeroup P2i /n with a = 12.694(2), b = 13.281 (4), c = 15.420(3) Ä, ß = 111.25(2)°, V = 2422.9(9) A ? ,Z = 2 . The molecule is a “linear” trinuclear complex with nearly...

Proton transfer in pyrazole systems involving interaction with a paramagnetic transition metal complex has been studied with 1H and 13C NMR techniques. Kinetics of the ligand exchange in the pyrazole complex of bis-(acetylacetonato)nickel (II) has been investigated, and hyperfine coupling constants for the interaction of the nickel unpaired electron with the ligand nuclei in the complex have be...

The asymmetrical tripodal tetraamine ligand N[(CH2)3NH2]2[(CH2)2NH2] (ppe) was condensed with 2-acetylpyridine in the presence of nickel(II) ion. In ethanolwater solution the reaction stops after the first stage of condensation, and a new nickel(II) complex of an acyclic pentadentate (N5) mono Schiff base ligand was obtained. X-ray structure analysis of the resulting complex, [Ni(ppe-py)(H2O)](...

Nickel(II) complexes of thiosemicarbazons were observed to be potent cytotoxic agents in human and rodent tissue cultured tumor cells. Each compound demonstrated a slightly different profile in the various histological types of tumors. The nickel complex of Appip demonstrated the most potent in vivo activity in the Ehrlich ascites carcinoma. This agent selectively inhibited L1210 DNA and purine...

STUDY OBJECTIVE To review reported adverse events associated with suspected nickel hypersensitivity and subsequent clinical outcomes in patients with Essure implants and to evaluate the correlation of nickel allergy-related adverse events with positive results of nickel patch testing. DESIGN Case series (Canadian Task Force classification II-3). MEASUREMENTS AND MAIN RESULTS Reports of susp...

BACKGROUND Nickel contact allergy is still frequent both in patch-tested patients and in the general population. Objectives. To explain this observation by relating clinical epidemiological data with recent chemical analyses of nickel release from costume jewellery. METHODS (i) The trend of nickel allergy was analysed using data registered between January 1994 and December 2009 in the Informa...

background: heavy metals in aquatic systems usually interfere with many beneficial uses of water. divalent nickel is a commonly occurring toxic metal in natural ecosystems due to the effluent of refineries, electroplating, and casting industries. in aquatic environments, nickel appears as ni (ii) and ni0. despite the high reported toxicity for ni (ii), ni0 is only slightly toxic. various method...

[Chemical reaction: See text] We describe efforts to achieve the electroreductive cyclization (ERC) and the electrohydrocyclization (EHC) reactions using catalytic nickel(II) salen as a mediator. While nickel(II) salen proved effective, the analogous cobalt complex as well as nickel(II) cyclam were not. The transformations were achieved in yields ranging from 60 to 94% using either a mercury po...

the use of colored semiconductor oxide like copper (ii) oxide and nickel (ii) oxide for photocatalytic bleaching of rose bengal was investigated in detail. in order to harness the solar energy, the effective wavelength of the photocatalyst is to be expanded into the visible region and that increases the rate of photocatalytic bleaching of the dye. progress of the reaction was observed spectroph...

A series of four-coordinate square-planar nickel(II) complexes of o-phenylenebis(N'-methyloxamidate)(L1) and related o-phenylene(N'-methyloxamidate)oxamate (L2) and o-phenylenebis(oxamate)(L3) tetradentate ligands have been synthesized and characterized structurally, spectroscopically and electrochemically. The parent nickel(II)-L1 complex presents an intense MLCT band in the UV region (lambda ...