in this work the acidity constants of thiamine in water and water-triton x-100 micelle media solutions, at 25 °c, have been determined spectrophotometrically. to evaluate the ph- absorbance data, a resolution based on the combination of soft-and hard-modeling is applied. the acidity constants of all related equilibria are estimated using the whole spectral fitting of the collected data to an es...

conclusions this study revealed that the administration of 600 μg of intravenous se immediately before induction of anesthesia was safe, but when compared to a placebo, no predominant clinical effects or modifications in the systemic inflammatory response induced by on-pump cabg were observed. results data from a total of 81 patients were analyzed: group s (n = 41) and group c (n = 40). there w...

3-(2-furanyl)-2-propenoic acid has been used to prepare a new series of organotin complexes of general formula r3snl (r=me, et, n-bu, ph and cy) and r2snl2 (r=me and n-bu). these complexes have been characterized by elemental analyses, ir, 1h-nmr, mass and mössbaure spectroscopy.

in the present work, b-zsm-5 zeolite membranes were synthesized on porous tubular α-alumina supports by several subsequence in situ crystallization hydrothermal treatments. the tio2- bohmite and ɣ- alumina intermediate layers were applied to improve the lattice matching between zeolite layer and the support. the uniform membrane intermediate layers with low permeation resistance were prepared o...

our aim in this work is the synthesis and study optical and structural properties of gold nanoparticles.gold (iii) chloride trihydratewas taken as metal precursor, ascorbic acid at the presence of an appropriate amount of naoh as reducing agent and polyvinylpyrrolidonek-30 (pvp k-30) as a stabilizing and capping agent. the reaction was performed in high-speed stirring rate at room temperature.s...

s i n c e t h e l a t e 1960s, s e v e r a l c o n s t i t u t i v e m o d e l s h a v e b e e n d e v e l o p e d f o r s a n d s d e s c r i b i n g t h e i r s t r e s s-s t r a i n e h a v i o r. m o s t o f t h e s e m o d e l s w e r e e s t a b l i s h e d b a s e d o n a m e a s u r e o f t h e p l a s t i c w o r k a n d s o m e y i e l d c r i t e r i a, a m o n g t h e m b e i n g t ...