The ability of chelated Gd to serve as an effective magnetic resonance (MR) contrast agent largely depends on fast exchange rates between the Gd-bound water molecules and the surrounding bulk water. Because water diffuses slowly across lipid bilayers, liposomes with encapsulated chelated Gd have not been widely adopted as MR contrast agents. To overcome this limitation, we have synthesized chem...

X-ray magnetic circular dichroism XMCD is the difference in absorption of leftand right-circularly polarized x-rays by a magnetized sample. Although MCD with x-rays is only about 15 years old, the physics is essentially the same as for UV-visible MCD that has been known since 1897. For (bio)inorganic chemists and materials scientists, XMCD has the advantage of elemental specificity that comes w...

We show that the energy-level splitting that arises from grain rotation ensures that paramagnetic dissipation acts at its maximum rate, i.e., the conditions for paramagnetic resonance are automatically fulfilled. We refer to this process as "resonance relaxation." The differences between the predictions of classical Davis-Greenstein relaxation and resonance relaxation are most pronounced for gr...

Changes are induced in the electron spin resonance signal amplitude and microwave power saturation of the naturally occurring free radical in melanin by bound paramagnetic ions. The changes serve as experimental observables in competition experiments between diamagnetic and paramagnetic metal ions for melanin binding sites and between melanin and ethylenediaminetetraacetic acid for paramagnetic...

There is considerable controversy surrounding the nature of the paramagnetic to ferromagnetic phase transition in La(0.7)Ca(0.3)MnO3. We have used transmission electron microscopy to determine whether the phase transition is first or second order. On warming through the transition point, the ferromagnetic phase retreats from the sample surface as it is replaced by the paramagnetic phase. This c...

A mechanism of enhanced paramagnetic relaxation for rapidly rotating interstellar grains is presented. We show that the Barnett magnetization that arises from grain rotation ensures that paramagnetic absorption happens at its maximum efficiency, i.e. the conditions for paramagnetic resonance are automatically fulfilled. The differences between the predictions of classical Davis-Greenstein relax...

We have demonstrated spin pumping from a paramagnetic state of an insulator La2NiMnO6 into a Pt film. Single-crystalline films of La2NiMnO6 which exhibit a ferromagnetic order at TC≈270  K were grown by pulsed laser deposition. The inverse spin Hall voltage induced by spin-current injection has been observed in the Pt layer not only in the ferromagnetic phase of La2NiMnO6, but also in a wide te...

The β-diketiminate ligand framework is shown to undergo reduction to form a neutral main group radical stabilized by spiroconjugation of the unpaired electron over the group 13 element centre. The synthesized paramagnetic complex was characterized by EPR spectroscopy and computational chemistry.

Hyperpolarization via dissolution dynamic nuclear polarization (DNP) is a versatile method to dramatically enhance the liquid-state NMR signal of X-nuclei and can be used for performing metabolic and molecular imaging. It was recently demonstrated that instead of incorporating persistent radicals as source of unpaired electron spins, required for DNP, nonpersistent radicals can be photoinduced ...