Dense Pd membranes are receiving significant attention for hydrogen separation in advanced coal-conversion processes because of their high hydrogen permeability and their nearinfinite selectivity. However, pure Pd is susceptible to hydrogen embrittlement as a result of the expansion of the Pd lattice during β-Pd-hydride formation. Furthermore, H2S, a coal gasification byproduct, severely inhibi...

A mercury plating technique was used to determine the phases forming on experimental Ag-Sn-Cu alloy powders (with and without Pd) exposed to electrolytically deposited mercury. Four series of alloy powders were made: a) 1.5% Pd with 10-14% Cu (CU series); b) 1.0% Pd with 10-14% Cu (1PD series); c) 1.5% Pd with different ratios of Ag3Sn (gamma) to Ag4Sn (beta) with 12% Cu (AGSN series); and d) 9...

A Pd/α-Al2O3 nanocatalyst with ultra-low Pd loading exhibits high activity and stability for CO oxidative coupling to dimethyl oxalate, which was prepared by a Cu(2+)-assisted in situ reduction method at room temperature. The small size and high dispersion of Pd nanoparticles facilitated by Cu(2+) ions are responsible for the excellent catalytic activity.

Structures, electronic, and magnetic properties of transition metal (TM) inserted W6O18 clusters have been investigated by using density functional theory. The Ti@W6O18, Ni@W6O18, Zr@W6O18, Rh@W6O18, W@W6O18, Ir@W6O18 are more structurally stable while the V@W6O18, Fe@W6O18, Zn@W6O18, Y@W6O18, Nb@W6O18, Pd@W6O18, La@W6O18, Re@W6O18, Hg@W6O18 chemically stable. amount charge transfer between TM ...

Cu doping of ZnTe, which is an important semiconductor for various optoelectronic applications, has been successfully achieved previously by several techniques. However, besides its electrical transport characteristics, other physical and chemical properties of heavily Cu-doped ZnTe have not been reported. We found an interesting self-assembled formation of crystalline well-aligned Cu-Te nano-r...

A comprehensive study of the interaction of transition metal clusters with B, C, N, O, and Si reveal novel structure and properties: Co12C6, Mn12C6, and Mn24C18 clusters form stable ferromagnetic hollow cages with total magnetic moments of 14 μB, 38 μB, and 70 μB, respectively. Replacement of C with B, N, O, or Si has significant impact on their structure and magnetic properties. For example, M...

With using the carbon nano-tube (CNT) of high chemical activity, nano-TiCx particles with different growth shapes were synthesized through the self-propagating high temperature in the 80 wt.% metal (Cu, Al, and Fe)-Ti-CNT systems. The growth shapes of the TiCx particles are mainly octahedron in the Cu- and Al-Ti-CNT systems, while mainly cube- and sphere-like in the Fe-Ti-CNT system.

C/Cu sheath/core nanocable arrays were mass-produced on various substructures, such as Si, SiO(2), Cu or glass, by using a one-step low-temperature metal-organic chemical vapor deposition. The novel nanostructures consist of a faceted Cu nanowire core with six side surfaces and four top surfaces, and a sheath of carbon. The as-synthesized nanocables are demonstrated excellent oxidization resist...

The hydrogen permeance of several 0.1 mm thick Pd–Cu alloy foils (80 wt.% Pd–20 wt.% Cu, 60 wt.% Pd–40 wt.% Cu and 53 wt.% Pd–47 wt.% Cu) was evaluated using transient flux measurements at temperatures ranging from 603 to 1123 K and pressures up to 620 kPa both in the presence and absence of 1000 ppm H2S. Sulfur resistance, as evidenced by no significant change in permeance, was correlated with...