Cobalt oxide has good catalytic activity for peroxydisulfate (PDS) activation but poor stability and is vulnerable to inactivation because of agglomeration. In this work, the chlortetracycline (CTC) degradation by catalysis using reduced graphene support cobalt (Co3O4/rGO) composite catalyst was investigated. It found that 86.3% CTC degraded within 120 min in Co3O4/rGO-800/PDS system. The influ...

In this work, the decomposition of phenanthrene (PHE) in mimic and real soil washing (SW) effluents was investigated using UVB light assisted activation hydrogen peroxide (H2O2) peroxydisulfate (PDS) oxidation processes. The impact oxidant concentration, initial pH, coexisting inorganic anions (Cl?, HCO3? NO3?) on PHE removal evaluated. degradation efficiency under irradiation followed order UV...

Bismuth oxyhalide, usually employed as a photocatalyst, has not been tested as an activator of peroxide for water purification. This work explores the potential application of bismuth oxyhalide (BiOX, X = Cl, Br, I)-activated peroxide (H2O2; peroxymonosulfate (PMS) and peroxydisulfate) systems for the degradation of carbamazepine (CBZ) in water destined for drinking water. BiOBr showed the high...

The preparation, characterization, fluorescence (FL) and electrochemiluminescence (ECL) of graphite-like carbon nitride nanoflake particles (g-C(3)N(4) NFPs) and nanoflake films (g-C(3)N(4) NFFs) have been reported. Highly water-dispersible g-C(3)N(4) NFPs with a height of ~5 to 35 nm and a lateral dimension of ~40 to 220 nm have been extracted from bulk g-C(3)N(4) materials by chemical oxidati...

New computational insights into the mechanism of the Boyland-Sims oxidation of arylamines with peroxydisulfate (S(2)O(8)(2-)) in an alkaline aqueous solution are presented. The key role of arylnitrenium cations, in the case of primary and secondary arylamines, and arylamine dications and immonium cations, in the case of tertiary arylamines, in the formation of corresponding o-aminoaryl sulfates...

This study was carried out in two stages. In the first stage; 2-oxo-2-phenylethyl-2-aminobenzoate (OPA) compound, which an aniline derivative, synthesized by starting appropriate components. Then, poly(OPA) obtained via chemical polymerization of OPA presence ammonium peroxydisulfate (APS) as initiator and DMF solvent. Poly(OPA)/Bentonite (BNT) nanocomposite effectively dispersing inorganic nan...

Polymeric carbon nitride (PCN) has great potential for peroxydisulfate (PDS) activation but still challenge due to the sluggish electron-hole pair dissociation and tardy charge transfer dynamics. Herein, a novel PCN-based donor-acceptor conjugated polymer (PCN/4-MI D-A) is synthesized by copolymerization of urea 4-methoxyphenyl isothiocyanate. The obtained PCN/4-MI D-A exhibited significantly i...