Carborane-intercalated layered double hydroxide nanohybrids (CB-LDH) and a magnesium ferrite (MF) supported-CB-LDH core-shell nanocomposite (CB-LDH@MF) are reported. The preparation of nanohybrids were carried out by exchanging the interlayer nitrate groups of Mg-Al-NO3-LDH with monothiol-o-carborane (SCB), 1-methyl-2-carboxyl-o-carborane (MeCB), 1-phenyl-2-carboxyl-o-carborane (PhCB) and 1,12-...

The relative (to BEt3) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for [Ph3C]+. The HIA at the acridine C9 position is controlled by both acridine and the boron substituents, the latter presumably affecting the strength of the B=N bond in the acridane-BY2 products from hydride transfer. Through a range of hydr...

Butadiene Produces a Hexameric Product. Subhasis De, Cynthia S. Day, and Mark E. Welker* Department of Chemistry, Wake Forest University, P.O. Box 7486, Winston-Salem, NC 27109 An unusual hexameric structure has been isolated from exposure of 3-BF3-1-Phenyl-1,3Butadiene to air and moisture in an attempt to obtain crystals of the starting compound. Formation of this hexamer is rationalized and i...

Two heterocyclic cyclopentadienyl analogs with a CB2N2 skeleton, 4-methyl-1,2,3,5-tetraphenyl-1,2-diaza-3,5-diborolidine and 4-methyl-3,5-dimethylamino-1,2-diphenyl-1,2-diaza-3,5-diborolidine were prepared through cyclocondensation of the corresponding 1,1-bis(organochloroboryl)ethane with 1,2-diphenylhydrazine. The former diazadiborolidine featured a cyclopentadiene-like structure with short B...

Two new dicyanovinyl (DCV) functionalized triarylboranes (Mes2B-π-spacer-DCV, for 1: π-spacer = C6H4, for 2: π-spacer = 2,3,5,6-tetramethyl-phenyl) are reported. The molecular structures of 1 and 2 are similar except for the spacer which connects the boryl and DCV units. This small structural perturbation induces drastic changes in the optical properties of 1 and 2. Compound 2 shows weak dual f...

cotton (gossypium hirsutum l. cv. varamin ) an important industrial crop of iran, is grown in 300,000 ha, with an average seed -cotton yield of 1750 kg.ha-1. the main obstacle in the way of increasing average cotton yield is imbalanced fertilizer use. along with urea and triple super phosphate, cotton growers also need k, mg, zn, fe, mn, cu, and b, so these elements’ critical levels should ...

Abstract The structure of antioxidants significantly affects the anti-migration and thermal-oxidative aging properties nitrile butadiene rubber (NBR) composites, which are crucial for applications in aerospace, biomedical, fuel cell stack sealing industries. findings reveal that migration rate N -(4-anilino phenyl) maleic imide (MC), with a reactive double bond, is only 15.6%, exhibiting best e...

Boron is an interesting element with unusual polymorphism. While three-dimensional (3D) structural motifs are prevalent in bulk boron, atomic boron clusters are found to have planar or quasi-planar structures, stabilized by localized two-center-two-electron (2c-2e) σ bonds on the periphery and delocalized multicenter-two-electron (nc-2e) bonds in both σ and π frameworks. Electron delocalization...

Borocaptate sodium (Na2B12H11SH) is a potentially useful compound for boron neutron capture therapy of intracranial tumors. Tumor and normal tissue boron concentrations were evaluated in 30 dogs with naturally occurring intracranial tumors after i.v. borocaptate sodium infusion (55 mg boron/kg). Postmortem tissue boron concentrations were measured for three postinfusion time periods (2, 6, and ...