The alteration of two trioctahedral micas, biotite and phlogopite, was investigated at the meso, micro, nanoscale using three complementary microscopy techniques to better understand mica surface reactivity. In situ ex experiments were performed monitor mineral interface during dissolution in acidic solutions (nitric oxalic acid, pH ∼ 1–2), over a temperature range 25–100°C. inorganic acid used...