نتایج جستجو برای: pitzer thermodynamic model
تعداد نتایج: 2134047 فیلتر نتایج به سال:
in this study, artificial neural network was used to predict the surface tension of 20 hydrocarbon mixtures. experimental data was divided into two parts (70% for training and 30% for testing). optimal configuration of the network was obtained with minimization of prediction error on testing data. the accuracy of our proposed model was compared with four well-known empirical equations. the arti...
the thermodynamic properties of fluids can be predicted using the global equations of state. among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. this paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. we also present a comparison of the crossover model equation with the experi...
abstract part one: the electrode oxidation potentials of a series of eighteen n-hydroxy compounds in aqueous solution were calculated based on a proper thermodynamic cycle. the dft method at the level of b3lyp-6-31g(d,p) was used to calculate the gas-phase free energy differences ,and the polarizable continuum model (pcm) was applied to describe the solvent and its interaction with n-hydroxy ...
A model for the solubility of methane in brines (O-6 m) for temperatures from 0 to 250°C and for pressures from 0 to 1600 bar (or slightly above) is presented. The model is based on Pitzer phenomenology for the liquid phase and a highly accurate equation of state recently developed for the vapor phase. Comparison of model predictions with experimental data indicates that they are within experim...
Bayesian inference is intractable for many interesting models, making deterministic algorithms for approximate inference highly desirable. Unlike stochastic methods, which are exact in the limit, the accuracy of these approaches cannot be reasonably judged. In this paper we show how low order perturbation corrections to an expectation-consistent (EC) approximation can provide the necessary tool...
In this work, the adsorption behavior of Sr onto a synthetic iron(III) oxide (hematite with traces goethite) has been studied. This solid, which might be considered representative Fe3+ solid phases (iron corrosion products), was characterized by X-Ray Diffraction (XRD) and Photoelectron Spectroscopy (XPS), its specific surface area determined. Both XRD XPS data are consistent mixed containing m...
In this study, the phase diagram and thermodynamic properties of Ti-O system up to 30 mole percent of oxygen was calculated with Calphad method. In this range of oxygen, Ti-O system includes αTi, βTi and liquid phases. αTi and βTi were modeled by “sublattice” model and the model of liquid phase was modeled by “ionic liquid”. Gibbs energy parameters ...
Myocardial heating by transcatheter delivery of radiofrequency (RF) energy has been proposed as an effective means of arrhythmia ablation. A thermodynamic model describing the radial temperature gradient at steady state during RF-induced heating is proposed. If one assumes that RF power output is adjusted to maintain a constant electrode-tissue interface temperature at all times, then this ther...
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