We describe an approach for characterizing selective binding between oppositely charged ionic functional groups under biologically relevant conditions. Relative shifts in K-shell x-ray absorption spectra of aqueous cations and carboxylate anions indicate the corresponding binding strengths via perturbations of carbonyl antibonding orbitals. XAS spectra measured for aqueous formate and acetate s...

Macromolecular sedimentation in inhomogeneous media is of great practical importance. Dynamic density gradients have a long tradition in analytical ultracentrifugation, and are frequently used in preparative ultracentrifugation. In this paper, a new theoretical model for sedimentation in inhomogeneous media is presented, based on finite element solutions of the Lamm equation with spatial and te...

The effect of temperature in the range of 0–150 8C was studied for homoionic montmorillonite clays with Na and Csqq compensating ions in low hydration states. Both static and dynamic information concerning the interlayer ions and water moleculeswas obtained by Monte Carlo and molecular dynamics. Principal structural changes were limited to the water phase, markeddifference was o...

In this study, the effect of variety of Nano- additives doping on the hydration resistance of the MgO-CaO system was investigated. Samples were prepared from calcined dolomite and magnesite. Nano-additives that contained cations with various valences (trivalent and tetravalent) used as  a dopant. The bulk density, apparent porosity and hydration resitance were studied and evaluated. Also, phase...

To explain the large, opposite effects of urea and glycine betaine (GB) on stability of folded proteins and protein complexes, we quantify and interpret preferential interactions of urea with 45 model compounds displaying protein functional groups and compare with a previous analysis of GB. This information is needed to use urea as a probe of coupled folding in protein processes and to tune mol...

In this study the effect of nano meter size ZrO2 particles on the microstructure, densification and hydration resistance of magnesite –dolomite refractories was investigated. 0, 2, 4, 6 and 8 wt. % ZrO2 particles that were added to magnesite –dolomite refractories containing 35 wt. % CaO. The Hydration resistance was measured by change in the weight of specimens after 72 h at 25℃ an...

introduction: preferential flow is one of the major processes influencing the rapid movement of pollutants to ground water.  macropores created by plant roots provide pathways for rapid transport of pollutants in a soil profile. the growth of plant roots into soil causes creation of big pores that improve water movement and solute transport through soil profile. field soils or undisturbed soils...

in this paper we study a representation of a fuzzy subgroup $mu$ of a group $g$, as a product of indecomposable fuzzy subgroups called the components of $mu$.  this representation is unique up to the number of components and their isomorphic copies. in the crisp group theory, this is a well-known theorem attributed to remak, krull, and schmidt. we consider the lattice of fuzzy subgroups and som...