In this report, the synthesis, characterization, and application of the eggshell-supported-Cu(II) salophen complex, as a novel and heterogeneous catalyst, is described. The catalyst is characterized by the UV, XRD, FT-IR, and SEM techniques. The eggshell-supported-Cu(II) salophen complex is a versatile, green, inexpensive, and simple catalyst used for the multi-component reactions (MCRs) of ter...

In this report, the synthesis, characterization, and application of the eggshell-supported-Cu(II) salophen complex, as a novel and heterogeneous catalyst, is described. The catalyst is characterized by the UV, XRD, FT-IR, and SEM techniques. The eggshell-supported-Cu(II) salophen complex is a versatile, green, inexpensive, and simple catalyst used for the multi-component reactions (MCRs) of ter...

In the present research, an efficient process for the synthesis of propargylamine derivatives catalyzed by a novel nanocomposite of CuO/MnO2 is reported. CuO/MnO2 nano-catalyst was synthesized by the co-precipitation process and characterized by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction(XRD), ICP-OES and BET surface area an...

A series of phosphanes with imidazolyl substituents were prepared as hemilabile PN ligands. The corresponding gold(I) complexes were tested as bifunctional catalysts in the Markovnikov hydration of 1-octyne, as well as in the synthesis of propargylamines by the three component coupling reaction of piperidine, benzaldehyde, and phenylacetylene. While the activity in the hydration of 1-octyne was...

Post-synthesis modification is a useful method for the functionalization of metal-organic frameworks (MOFs). A novel catalyst Au@MIL-101-ED-SA (ED = ethylenediamine, SA = salicylaldehyde), containing coexisting Au3+ ions and Au⁰ nanoparticles, was prepared successfully by post-synthesis modification with ethylenediamine, salicylaldehyde and gold. Gold nanoparticles supported on MIL-101 (Au@MIL-...