für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

We present the analysis on the quadrupole phases of the Internal Linear Combination map, ILC(I) and (III) derived by the WMAP team (1 and 3-year data release). This approach allows us to see the global trend of non-Gaussianity of the quadrupoles for the ILC(III) map through phase correlations with the foregrounds. Significant phase correlations is found in between the ILC(III) quadrupole and th...

The far-infrared vibration-rotation spectrum of the out-of-plane DC1 bending band of Ar2-DC1 is observed around 36.0cm -1. The experimental bending frequency, rotational constants and hyperfine coupling constants are compared with the results of calculations employing both pairwise-additive and non-additive interaction potentials. As found previously for Ar2-HC1, there are substantial discrepan...

Proton and oxygen-17 nmr relaxation rates of C D 3 1 7 O H as well as deuteron nmr relaxation rates of C H 3 O D were measured in mixtures with carbon tetrachloride at different compositions and temperatures. By varying the 1 0-content different contributions to the proton relaxation rate could be separated and from the 1 7 0 H dipolar interaction contribution the correlation time of the O H bo...

By single crystal C1-NQR Zeeman spectroscopy, the five independent C1 nuclear quadrupole coupling tensors in a-parachloral, (Cl3CCHO)3, have been studied at 24 ± 2 °C. The directions of the electric field gradient (EFG) tensor components have been determined. The principal axes are within ± 0.8° parallel to the C-Cl bond directions found by X-ray diffraction. Very small asymmetry parameters in ...

The normalized elimination of the small component (NESC) method is a Dirac-exact relativistic method that leads to reliable first order response properties such as contact densities, Mössbauer shifts, electric field gradients, quadrupole coupling constants, or hyperfine structure constants for heavy atoms. In this review, the calculation of these hyperfine parameters with a NESC analytical deri...