In the title mol-ecule, C11H10ClFO2, the benzene ring, the F atom and the O atom of the di-hydro-pyran ring are essentially coplanar, with an r.m.s. deviation of 0.007 Å. The di-hydro-pyran ring is in a half-chair conformation. In the crystal, mol-ecules are linked by pairs of weak C-H⋯π hydrogen bonds, forming inversion dimers.

In the title compound, C20H22N2O2, the central pyridine ring forms a dihedral angle of 76.32 (8)° with the pseudo-axial benzene ring. The cyclo-octane ring adopts a twisted boat chair conformation. In the crystal, weak inter-molecular C-H⋯π inter-actions between inversion-related mol-ecules result in the formation of linear double chains along the b-axis direction.

In the title compound, C(25)H(22)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 32.02 (14), 37.49 (18) and 80.52 (13)°, respectively, with the pyrazolone ring, the bromo-benzene ring and the terminal phenyl ring. This conformation features a short intramolecular C-H⋯O contact that generates an S(6) ring. In the crystal, inversion dimers linked by pairs of C-H⋯O=C hydrogen bonds ...

In the title compound, C15H14ClNO2S2, the 2H-chromene ring system is essentially planar, with a maximum deviation of 0.0133 (10) Å. Three C atoms and their attached H atoms of the pyrrolidine ring are disordered [occupany ratio 0.874 (7):0.126 (7)] with both disorder components adopting a twisted conformation. The dihedral angle between the 2H-chromene ring system and the major occupancy compon...

In the title compound, C(10)H(10)ClN(5)O(2), the dihedral angle between the aromatic rings is 0.16 (9)°. Two S(6) ring motifs are formed due to intra-molecular N-H⋯N and N-H⋯O hydrogen bonds. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(14) [or R(4) (4)(10) via the intra-molecular hydrogen bonds] ring motifs. Polymeric chains propagating in [210] ar...

In the title compound, C(14)H(15)NO(3)S, the geometry around the S atom of the SO(2) group is distorted tetra-hedral. The meth-oxy- and methyl-substituted aromatic rings are oriented at a dihedral angle of 71.39 (9)°. Inter-molecular N-H⋯O hydrogen bonds form inversion dimers, which stabilize the crystal structure.

In the title compound, C(18)H(19)N(3)O(2), the dihedral angle between the benzene rings is 20.47 (10)° and an intra-molecular N-H⋯O hydrogen bond occurs, generating an S(5) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds lead to R(2) (2)(8) loops.

In the crystal structure of the title compound, C(15)H(17)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -61.0 (2)°. The dihedral angle between the two aromatic rings is 49.4 (1)°. The crystal structure features inversion-related dimers linked by pair...

In the title compound, C(15)H(16)ClNO(2)S, the C-SO(2)-NH-C torsion angle is 67.45 (17)°. The two aromatic rings are tilted relative to each other by 44.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds..

In the title compound, C(14)H(15)N(5)O(4), the central -C=N-N-C(=O)-C- bridge is nearly planar [maximum deviation = 0.037 (1) Å] and forms dihedral angles of 7.37 (9) and 73.33 (5)°, respectively, with the benzene and imidazole rings. The dihedral angle between the benzene and imidazole rings is 66.08 (9)°. The meth-oxy and nitro groups are nearly coplanar with the benzene and imidazole rings, ...