Background Chronic stress induces male reproductive dysfunction; however, the involved mechanisms are not clear. It has been suggested that the gonadotrophin-inhibitory hormone, known as RF-amide related peptide (RFRP) in mammalian species, may mediate this inhibitory effect of stress. The objective of the present study was to compare the effect of chronic stress and glucocorticoids receptor an...

In this paper, rod-like chitin whisker was used as a filler to reinforce the chitosan membrane, and a series of composite membranes were prepared by casting-evaporation method. Mechanical testing shows that tensile strength of the resulting composite membrane with 3 wt% chitin whisker content reaches up to 110.3 MPa, which is about 2.8 times than that of neat chitosan membrane (38.5 MPa), and m...

Yeast iso-1-cytochrome c covalently modified at cysteine-102 with (4-bromomethyl-4'-methylbipyridine)[bis(bipyridine)]Ru2+ (Ru-102-Cyt c) has been used as a photoactive electron donor to mitochondrial cytochrome c oxidase (COX) reconstituted into phospholipid vesicles. Rapid kinetics of membrane potential generation by the enzyme following flash-induced photoreduction of Ru-102-Cyt c heme has b...

In the fusion reactor ITER, ammonia will be produced as a result of interaction between hydrogen isotopes used fuel and nitrogen to spread power loads larger area. As part management in NQ3 (NQ3, Q = H, D, T) have decomposed using palladium membrane reactor. The decomposition pure NH3 ND3 was studied this work commercial platinum (Pt) ruthenium (Ru) catalysts on alumina (0.5 wt% loading), conve...

Inorganic-organic composite electrolyte membranes were fabricated from CsXH3-XPMo12O40 (CsPOMo) and quaternary diazabicyclo-octane polysulfone (QDPSU) using a polytetrafluoroethylene (PTFE) porous matrix for the application of intermediate temperature fuel cells. The CsPOMo/QDPSU/PTFE composite membrane was made proton conducting by using a relatively low phosphoric acid loading, which benefits...

Giant liposomes containing Ru(bpy)(3)(2+) (bpy = 2,2'-bipyridine) were prepared as model systems for biomembranes and cells and studied by scanning electrochemical microscopy (SECM). Conical carbon fiber tips of submicrometer size were used to approach, image, and puncture individual liposomes immobilized on glass substrates. SECM images of the liposomes were obtained, and the leakage of Ru(bpy...

We evaluated the activities of well-defined Ru@Pt core-shell nanocatalysts for hydrogen evolution and oxidation reactions (HER-HOR) using hanging strips of gas diffusion electrode (GDE) in solution cells. With gas transport limitation alleviated by micro-porous channels in the GDEs, the charge transfer resistances (CTRs) at the hydrogen reversible potential were conveniently determined from lin...

The pathways involved in cellular uptake and accumulation of iminopyridine complexes of general formula [Ru(η(6)-p-cymene)(N,N-dimethyl-N'-[(E)-pyridine-2-ylmethylidene]benzene-1,4-diamine)X]PF(6) bearing two different halido ligands X = Cl or I, have been explored. The ratio of passive/active cellular accumulation of Ru in A2780 human ovarian cancer cells is compared and contrasted with cispla...

The encapsulation of homogeneous chiral catalysts, e.g. Co(Salen) and Ru-TsDPEN, in the mesoporous cage of SBA-16 is demonstrated; the encapsulated catalysts show performance as good as that of the homogeneous catalysts, and can be recycled for more than 10 times without significant loss of catalytic performance.

Transition metal complexes provide a promising avenue for the design of therapeutic and diagnostic agents, but the limited understanding of their cellular uptake is a roadblock to their effective application. Here, we examine the mechanism of cellular entry of a luminescent ruthenium(II) polypyridyl complex, Ru(DIP) 2dppz (2+) (where DIP = 4,7-diphenyl-1,10-phenanthroline and dppz = dipyridophe...